New rhodium(II) complexes with 2,2':6',2''-terpyridine

被引：46
|
作者：
Pruchnik, FP [1 ]
Robert, F [1 ]
Jeannin, Y [1 ]
Jeannin, S [1 ]
机构：
[1] UNIV PARIS 06, CHIM MET TRANSIT LAB, F-75252 PARIS, FRANCE
来源：
INORGANIC CHEMISTRY | 1996年 / 35卷 / 14期
关键词：
D O I：
10.1021/ic950529a
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The compounds [Rh-2(mu-OAc)(4)(terpy)(2)] (1) and [Rh2Cl2(mu-OAc)(terpy)(2)](H3O)Cl-2 .-9H(2)O (2) have been synthesized in reactions of [Rh-2(mu-OAc)(4)(H2O)(2)] with 2,2':6',2 ''-terpyridine (terpy) (compound 1) and with terpy and NaCl (compound 2) in ethanol using stoichiometric quantities of reactants. Both compounds were structurally and spectroscopically characterized. In 1 terpyridine acts as a monodentate ligand. The compound 2 is the first Rh(II) complex containing only one carboxylato bridging ligand to be analyzed crystallographically. The Rh-Rh distance in 1 is considerably shorter than in 2, The complex 2 in basic solutions in alcohols is an efficient catalyst for reduction of ketones.
引用
收藏
页码：4261 / +
页数：1
相关论文
共 50 条
  • [1] New Rhodium(II) Complexes with 2,2′:6′,2″-Terpyridine
    Faculty of Chemistry, University of Wroclaw, Joliot-Curie 14, 50-383 Wroclaw, Poland
    不详
    Inorg. Chem., 14 (4261-4263):
  • [2] NOVEL DIDENTATE 2,2'-6',2''-TERPYRIDINE COMPLEXES OF RUTHENIUM(II)
    CONSTABLE, EC
    THOMPSON, AMWC
    INORGANICA CHIMICA ACTA, 1994, 223 (1-2) : 177 - 179
  • [3] New Co(II) And Mn(II) Complexes with 4′-Substituted 2,2′:6′,2″-Terpyridine Ligands
    W.-W. Fu
    X. Shu
    Y.-L. Luo
    Z.-Q. Tang
    Q. Li
    H.-J. Liu
    Q.-W. Cheng
    H.-Y. Wang
    Y. Liu
    Journal of Structural Chemistry, 2018, 59 : 398 - 410
  • [4] NEW Co(II) AND Mn(II) COMPLEXES WITH 4′-SUBSTITUTED 2,2′:6′,2"-TERPYRIDINE LIGANDS
    Fu, W-W
    Shu, X.
    Luo, Y-L
    Tang, Z-Q
    Li, Q.
    Liu, H-J
    Cheng, Q-W
    Wang, H-Y
    Liu, Y.
    JOURNAL OF STRUCTURAL CHEMISTRY, 2018, 59 (02) : 398 - 410
  • [5] Homoleptic complexes of a porphyrinatozinc(II)-2,2′:6′,2"-terpyridine ligand
    Lanzilotto, Angelo
    Kuss-Petermann, Martin
    Wenger, Oliver S.
    Constable, Edwin C.
    Housecroft, Catherine E.
    PHOTOCHEMICAL & PHOTOBIOLOGICAL SCIENCES, 2017, 16 (04) : 585 - 595
  • [6] Homoleptic complexes of a porphyrinatozinc(ii)-2,2′:6′,2′′-terpyridine ligand
    Angelo Lanzilotto
    Martin Kuss-Petermann
    Oliver S. Wenger
    Edwin C. Constable
    Catherine E. Housecroft
    Photochemical & Photobiological Sciences, 2017, 16 : 585 - 595
  • [7] New ruthenium(II) complexes of 2,2′:6′,2"-terpyridine derivatives as supramolecular building blocks
    Shen, Chao
    Wang, Pi
    Beves, Jonathon E.
    POLYHEDRON, 2016, 103 : 241 - 247
  • [8] An improved method for the synthesis of (2,2':6',2''-terpyridine)platinum(II) complexes
    Lowe, G
    Vilaivan, T
    JOURNAL OF CHEMICAL RESEARCH-S, 1996, (08): : 386 - 387
  • [9] NMR study on Ru(II) complexes containing 2,2′:6′,2"-terpyridine
    Seok, WK
    Moon, SW
    Kim, MY
    BULLETIN OF THE KOREAN CHEMICAL SOCIETY, 1998, 19 (11) : 1207 - 1210
  • [10] Approaches to wired terpyridine: Bithienyl alkynyl derivatives of 2,2′:6′,2"-terpyridine and their ruthenium(II) complexes
    Constable, Edwin C.
    Figgemeier, Egbert
    Housecroft, Catherine E.
    Medlycott, Elaine A.
    Neuburger, Markus
    Schaffner, Silvia
    Reymann, Sebastien
    POLYHEDRON, 2008, 27 (18) : 3601 - 3606
12345