KINETICS OF LIQUID-PHASE SYNTHESIS OF ETHYL TERT-BUTYL ETHER FROM TERT-BUTYL ALCOHOL AND ETHANOL CATALYZED BY ION-EXCHANGE RESIN AND HETEROPOLY ACID

被引：28

作者：

YIN, XD ^{[1
]}

YANG, BL ^{[1
]}

GOTO, S ^{[1
]}

机构：

[1] NAGOYA UNIV,DEPT CHEM ENGN,CHIKUSA KU,NAGOYA,AICHI 46401,JAPAN

来源：

INTERNATIONAL JOURNAL OF CHEMICAL KINETICS | 1995年 / 27卷 / 11期

关键词：

D O I：

10.1002/kin.550271104

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Synthesis of ethyl tert-butyl ether (ETBE) from ethanol (EtOH) and tert-butyl alcohol (TBA) in the liquid phase was studied by using ion exchange resin, Amberlyst 15 (A15) in the H+ form and heteropoly acid, H0.5Cs3.5SiW12O40(HPA). Experiments were carried out in a stirred batch reactor with different temperatures under atmospheric pressure. It was found that water will inhibit the reaction rates greatly and the dehydration of TBA could not be neglected in this study. A kinetics model which considered the inhibition of water and the decrease of volume was proposed. The experimental results agreed well with the model. (C) 1995 John Wiley & Sons, Inc.

引用

页码：1065 / 1074

页数：10

共 50 条

[41] COMBINED PROCESS FOR PRODUCTION OF METHYL TERT-BUTYL ETHER FROM TERT-BUTYL ALCOHOL AND METHANOL
MATOUQ, M
TAGAWA, T
GOTO, S
JOURNAL OF CHEMICAL ENGINEERING OF JAPAN, 1994, 27 (03) : 302 - 306
[42] Compressed liquid densities of methyl tert-butyl ether (MTBE), ethyl tert-butyl ether (ETBE), and diisopropyl ether (DIPE)
Ihmels, EC
Gmehling, J
JOURNAL OF CHEMICAL AND ENGINEERING DATA, 2002, 47 (05): : 1307 - 1313
[43] Synthesis of methyl tert-butyl ether from tert-butyl alcohol and methanol using beta zeolite catalysts
Chen, JY
Ko, AN
REACTION KINETICS AND CATALYSIS LETTERS, 2000, 71 (01): : 77 - 83
[44] Synthesis of Methyl tert-Butyl Ether from tert-Butyl Alcohol and Methanol Using Beta Zeolite Catalysts
Jia-Yun Chen
An-Nan Ko
Reaction Kinetics and Catalysis Letters, 2000, 71 : 77 - 83
[45] Determination of adsorption and kinetic parameters for methyl tert-butyl ether synthesis from tert-butyl alcohol and methanol
Zhang, ZY
Hidajat, K
Ray, AK
JOURNAL OF CATALYSIS, 2001, 200 (02) : 209 - 221
[46] INFLUENCE OF WATER ON THE GAS-PHASE DECOMPOSITION OF METHYL TERT-BUTYL ETHER CATALYZED BY A MACROPOROUS ION-EXCHANGE RESIN
TEJERO, J
CUNILL, F
MANZANO, S
APPLIED CATALYSIS, 1988, 38 (02): : 327 - 340
[47] Liquid-phase synthesis of ethyl tert-butyl ether over acid cation-exchange inorganic-organic resins
Vlasenko, N. V.
Kochkin, Yu. N.
Topka, A. V.
Strizhak, P. E.
APPLIED CATALYSIS A-GENERAL, 2009, 362 (1-2) : 82 - 87
[48] Synthesis of ethyl tert-butyl ether on pellets cation exchange resins
Yang, Bolun
Yang, Sanba
Huagong Xuebao/Journal of Chemical Industry and Engineering (China), 2001, 52 (09): : 797 - 802
[49] Vapor-liquid equilibria and vapor pressure data for the systems ethyl tert-butyl ether plus ethanol and ethyl tert-butyl ether plus water
Rarey, J
Horstmann, S
Gmehling, J
JOURNAL OF CHEMICAL AND ENGINEERING DATA, 1999, 44 (03): : 532 - 538
[50] MASS-TRANSFER EFFECTS ON KINETICS OF NONIDEAL LIQUID-PHASE ETHYL TERT-BUTYL ETHER FORMATION
SUNDMACHER, K
ZHANG, RS
HOFFMANN, U
CHEMICAL ENGINEERING & TECHNOLOGY, 1995, 18 (04) : 269 - 277

← 1 2 3 4 5 →