KINETICS OF LIQUID-PHASE SYNTHESIS OF ETHYL TERT-BUTYL ETHER FROM TERT-BUTYL ALCOHOL AND ETHANOL CATALYZED BY ION-EXCHANGE RESIN AND HETEROPOLY ACID

被引：28
|
作者：
YIN, XD [1 ]
YANG, BL [1 ]
GOTO, S [1 ]
机构：
[1] NAGOYA UNIV,DEPT CHEM ENGN,CHIKUSA KU,NAGOYA,AICHI 46401,JAPAN
来源：
INTERNATIONAL JOURNAL OF CHEMICAL KINETICS | 1995年 / 27卷 / 11期
关键词：
D O I：
10.1002/kin.550271104
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Synthesis of ethyl tert-butyl ether (ETBE) from ethanol (EtOH) and tert-butyl alcohol (TBA) in the liquid phase was studied by using ion exchange resin, Amberlyst 15 (A15) in the H+ form and heteropoly acid, H0.5Cs3.5SiW12O40(HPA). Experiments were carried out in a stirred batch reactor with different temperatures under atmospheric pressure. It was found that water will inhibit the reaction rates greatly and the dehydration of TBA could not be neglected in this study. A kinetics model which considered the inhibition of water and the decrease of volume was proposed. The experimental results agreed well with the model. (C) 1995 John Wiley & Sons, Inc.
引用
收藏
页码：1065 / 1074
页数：10
相关论文
共 50 条
  • [31] Revision of microkinetic approaches to the liquid-phase synthesis of ethyl tert-butyl ether (ETBE)
    Schwarzer, S
    Horst, C
    Kunz, U
    Hoffmann, U
    CHEMICAL ENGINEERING & TECHNOLOGY, 2000, 23 (05) : 417 - 421
  • [32] Vapor-liquid equilibria and vapor pressure data for the systems ethyl tert-butyl ether + ethanol and ethyl tert-butyl ether + water
    Rarey, Jürgen
    Horstmann, Sven
    Gmehling, Jürgen
    Journal of Chemical and Engineering Data, 44 (03): : 532 - 538
  • [33] Kinetics of the simultaneous syntheses of ethyl tert-butyl ether (ETBE) and butyl tert-butyl ether (BTBE) over AmberlystTM 35
    Badia, Jordi H.
    Fite, Carles
    Bringue, Roger
    Cunill, Fidel
    Tejero, Javier
    CHEMICAL ENGINEERING SCIENCE, 2022, 264
  • [34] Kinetics of the simultaneous syntheses of ethyl tert-butyl ether (ETBE) and butyl tert-butyl ether (BTBE) over AmberlystTM 35
    Badia, Jordi H.
    Fité, Carles
    Bringué, Roger
    Cunill, Fidel
    Tejero, Javier
    Chemical Engineering Science, 2022, 264
  • [35] The first non-acid catalytic synthesis of tert-butyl ether from tert-butyl alcohol using ionic liquid as dehydrator
    Shi, F
    Xiong, H
    Gu, YL
    Guo, S
    Deng, YQ
    CHEMICAL COMMUNICATIONS, 2003, (09) : 1054 - 1055
  • [36] Photocatalytic oxidation of gas-phase methyl tert-butyl ether and tert-butyl alcohol
    Preis, S
    Falconer, JL
    Asensio, RD
    Santiago, NC
    Kachina, A
    Kallas, J
    APPLIED CATALYSIS B-ENVIRONMENTAL, 2006, 64 (1-2) : 79 - 87
  • [37] METHYL TERT-BUTYL ETHER AND ETHYL TERT-BUTYL ETHER - SYNTHESIS OVER TRIFLIC ACID MODIFIED Y-ZEOLITE
    LEVANMAO, R
    AHLAFI, H
    LE, TS
    ACS SYMPOSIUM SERIES, 1993, 517 : 233 - 243
  • [38] Reevaluation of microkinetic approaches to the liquid phase synthesis of ethyl tert-butyl ether
    Schwarzer, S
    Kunz, U
    Hoffmann, U
    CHEMIE INGENIEUR TECHNIK, 1999, 71 (08) : 864 - 868
  • [39] Byproducts formation in the ethyl tert-butyl ether (ETBE) synthesis reaction on macroreticular acid ion-exchange resins
    Badia, J. H.
    Fite, C.
    Bringue, R.
    Ramirez, E.
    Cunill, F.
    APPLIED CATALYSIS A-GENERAL, 2013, 468 : 384 - 394
  • [40] Liquid-phase synthesis of butyl tert-butyl ether catalysed by ion-exchange resins: kinetic modelling through in-depth model discrimination
    Badia, Jordi Hug
    Fite, Carles
    Bringue, Roger
    Ramirez, Eliana
    Iborra, Montserrat
    REACTION CHEMISTRY & ENGINEERING, 2021, 6 (01) : 165 - 172
12345