KINETICS OF LIQUID-PHASE SYNTHESIS OF ETHYL TERT-BUTYL ETHER FROM TERT-BUTYL ALCOHOL AND ETHANOL CATALYZED BY ION-EXCHANGE RESIN AND HETEROPOLY ACID

被引：28
|
作者：
YIN, XD [1 ]
YANG, BL [1 ]
GOTO, S [1 ]
机构：
[1] NAGOYA UNIV,DEPT CHEM ENGN,CHIKUSA KU,NAGOYA,AICHI 46401,JAPAN
来源：
INTERNATIONAL JOURNAL OF CHEMICAL KINETICS | 1995年 / 27卷 / 11期
关键词：
D O I：
10.1002/kin.550271104
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Synthesis of ethyl tert-butyl ether (ETBE) from ethanol (EtOH) and tert-butyl alcohol (TBA) in the liquid phase was studied by using ion exchange resin, Amberlyst 15 (A15) in the H+ form and heteropoly acid, H0.5Cs3.5SiW12O40(HPA). Experiments were carried out in a stirred batch reactor with different temperatures under atmospheric pressure. It was found that water will inhibit the reaction rates greatly and the dehydration of TBA could not be neglected in this study. A kinetics model which considered the inhibition of water and the decrease of volume was proposed. The experimental results agreed well with the model. (C) 1995 John Wiley & Sons, Inc.
引用
收藏
页码：1065 / 1074
页数：10
相关论文
共 50 条
  • [1] KINETICS OF LIQUID-PHASE SYNTHESIS OF METHYL TERT-BUTYL ETHER FROM TERT-BUTYL ALCOHOL AND METHANOL CATALYZED BY ION-EXCHANGE RESIN
    MATOUQ, MH
    GOTO, S
    INTERNATIONAL JOURNAL OF CHEMICAL KINETICS, 1993, 25 (10) : 825 - 831
  • [2] Synthesis of ethyl tert-butyl ether with tert-butyl alcohol and ethanol on various ion exchange resin catalysts
    Umar, Muhammad
    Saleemi, Anwar Rasheed
    Qaiser, Suleman
    CATALYSIS COMMUNICATIONS, 2008, 9 (05) : 721 - 727
  • [3] LIQUID-PHASE SYNTHESIS OF METHYL TERT-BUTYL ETHER CATALYZED BY ION-EXCHANGE RESIN
    SUBRAMANIAM, C
    BHATIA, S
    CANADIAN JOURNAL OF CHEMICAL ENGINEERING, 1987, 65 (04): : 613 - 620
  • [4] Kinetics of liquid phase synthesis of ethyl tert-butyl ether from tert-butyl alcohol and ethanol catalyzed by β-zeolite supported on monolith
    Assabumrungrat, S
    Kiatkittipong, W
    Sevitoon, N
    Praserthdam, P
    Goto, S
    INTERNATIONAL JOURNAL OF CHEMICAL KINETICS, 2002, 34 (05) : 292 - 299
  • [5] Reaction Equilibrium for the Liquid-Phase Simultaneous Decomposition of Methyl tert-Butyl Ether and tert-Butyl Alcohol over Ion-Exchange Resin
    Su, Wei-Bin
    Chang, Tse-Kuei
    Hwang, Jyh-Haur
    Huang, Hsun-Yi
    INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2015, 54 (34) : 8448 - 8455
  • [6] A pervaporation membrane reactor for liquid phase synthesis of ethyl tert-butyl ether from tert-butyl alcohol and ethanol
    Kiatkittipong, W
    Assabumrungrat, S
    Praserthdam, P
    Goto, S
    JOURNAL OF CHEMICAL ENGINEERING OF JAPAN, 2002, 35 (06) : 547 - 556
  • [7] Thermodynamic Study of Liquid Phase Synthesis of Ethyl tert-Butyl Ether Using tert-Butyl Alcohol and Ethanol
    Ozbay, Nalan
    Oktar, Nuray
    JOURNAL OF CHEMICAL AND ENGINEERING DATA, 2009, 54 (12): : 3208 - 3214
  • [8] Synthesis of ethyl tert-butyl ether from tert-butyl alcohol and ethanol on strong acid cation-exchange resins
    Yang, BL
    Yang, SB
    Yao, RQ
    REACTIVE & FUNCTIONAL POLYMERS, 2000, 44 (02): : 167 - 175
  • [9] Kinetics and mechanism of ethyl tert-butyl ether liquid-phase synthesis
    Francoisse, O., 1600, (30):
  • [10] Simulation of pervaporation membrane reactors for liquid phase synthesis of ethyl tert-butyl ether from tert-butyl alcohol and ethanol
    Assabumrungrat, S
    Kiatkittipong, W
    Praserthdam, P
    Goto, S
    CATALYSIS TODAY, 2003, 79 (1-4) : 249 - 257
12345