(Me4N)( NO2)(2)C6H3CO2 NEW MCl2 (M = Zn, Co, Cd) AND SnR3Cl (R = Me, Ph) ADDUCTS: SYNTHESIS AND INFRARED STUDY

被引：0

作者：

Traore, Bocar ^{[1
]}

Diop, Libasse ^{[1
]}

Sidibe, Mamadou ^{[1
]}

机构：

[1] Univ Cheikh Anta Diop, Fac Sci & Tech, Dept Chim, Lab Chim Minarale & Analyt LACHIMIA, Dakar, Senegal

来源：

SCIENTIFIC STUDY AND RESEARCH-CHEMISTRY AND CHEMICAL ENGINEERING BIOTECHNOLOGY FOOD INDUSTRY | 2013年 / 14卷 / 02期

关键词：

NO2C6H3CO2](-); ligand; infrared; discrete; structures;

D O I：

暂无

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Five new (Me4N)(NO2)(2)C6H3CO2 adducts with MCl2 (M = Zn, Co, Cd) and SnR3Cl (R = Me, Ph) have been synthesized and studied by infrared spectroscopy. The suggested structures are discrete, the anion behaving as mono-and bichelating ligand towards MX2, tri-and monodentate towards SnR3Cl (R = Me, Ph). The environment around Zn, Co and Cd is tetrahechal, while the tin (IV) centre is trigonal bipyramidal.

引用

页码：119 / 122

页数：4

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