(Me4N)( NO2)(2)C6H3CO2 NEW MCl2 (M = Zn, Co, Cd) AND SnR3Cl (R = Me, Ph) ADDUCTS: SYNTHESIS AND INFRARED STUDY

被引：0
|
作者：
Traore, Bocar [1 ]
Diop, Libasse [1 ]
Sidibe, Mamadou [1 ]
机构：
[1] Univ Cheikh Anta Diop, Fac Sci & Tech, Dept Chim, Lab Chim Minarale & Analyt LACHIMIA, Dakar, Senegal
来源：
SCIENTIFIC STUDY AND RESEARCH-CHEMISTRY AND CHEMICAL ENGINEERING BIOTECHNOLOGY FOOD INDUSTRY | 2013年 / 14卷 / 02期
关键词：
NO2C6H3CO2](-); ligand; infrared; discrete; structures;
D O I：
暂无
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Five new (Me4N)(NO2)(2)C6H3CO2 adducts with MCl2 (M = Zn, Co, Cd) and SnR3Cl (R = Me, Ph) have been synthesized and studied by infrared spectroscopy. The suggested structures are discrete, the anion behaving as mono-and bichelating ligand towards MX2, tri-and monodentate towards SnR3Cl (R = Me, Ph). The environment around Zn, Co and Cd is tetrahechal, while the tin (IV) centre is trigonal bipyramidal.
引用
收藏
页码：119 / 122
页数：4
相关论文
共 50 条
  • [21] Synthesis and characterization of the [Ru(η5-C5Me4CF3)(CO)2]2 and Ru6(μ3-H)(η2-μ4-CO)2(μ-CO)(CO)12(η5-C5Me4CF3) complexes
    Z. A. Kerzina
    M. I. Rybinskaya
    F. M. Dolgushin
    A. I. Yanovsky
    P. V. Petrovskii
    E. Kolehmainen
    Russian Chemical Bulletin, 1998, 47 : 490 - 495
  • [22] Synthesis and characterization of the [Ru(η5-C5Me4CF3)(CO)2]2 and Ru6(μ3-H)(η2-μ4-CO)2(μ-CO)(CO)12(η5-C5Me4CF3) complexes
    Kerzina, ZA
    Rybinskaya, MI
    Dolgushin, FM
    Yanovsky, AI
    Petrovskii, PV
    Kolehmainen, E
    RUSSIAN CHEMICAL BULLETIN, 1998, 47 (03) : 490 - 495
  • [23] Molecular Structures of RN(H)Py (R = 2,4,6-Me3C6H2, 2,6-Et2C6H3, Ph3C), and the Copper Complex [Cu{(2,4,6-Me3C6H2)N(H)Py}2]BF4
    John J. Allen
    Christopher E. Hamilton
    Andrew R. Barron
    Journal of Chemical Crystallography, 2009, 39 : 573 - 580
  • [24] Molecular Structures of RN(H)Py (R=2,4,6-Me3C6H2, 2,6-Et2C6H3, Ph3C), and the Copper Complex [Cu{(2,4,6-Me3C6H2)N(H)Py}2]BF4
    Allen, John J.
    Hamilton, Christopher E.
    Barron, Andrew R.
    JOURNAL OF CHEMICAL CRYSTALLOGRAPHY, 2009, 39 (08) : 573 - 580
  • [25] Synthesis and Reactivity of Ir(I) and Ir(III) Complexes with MeNH2, Me2C=NR (R = H, Me), C,N-C6H4{C(Me)=N(Me)}-2, and N,N′-RN=C(Me)CH2C(Me2)NHR (R = H, Me) Ligands
    Vicente, Jose
    Chicote, Maria Teresa
    Vicente-Hernandez, Inmaculada
    Bautista, Delia
    INORGANIC CHEMISTRY, 2008, 47 (20) : 9592 - 9605
  • [26] REACTIONS OF THE ACETYLENE-COMPLEX, (C6H3ME3)(CO)2CR(C2H2), WITH PME3 AND HNME2 - SOLID-STATE STRUCTURE OF (C6H3ME3)(CO)2CR(PME3) AND (C6H3ME3)(CO)2CR[C(ME)NME2]
    ROGERS, RD
    ALT, HG
    ENGELHARDT, HE
    JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1989, 366 (03) : 305 - 312
  • [27] Synthesis, structures and thermal rearrangement reaction of (Me2SiGeMe2)[(η5-C5R4)Fe(CO)]2(μ-CO)2 (R = H, Me)
    Sun, XL
    Wang, BQ
    Xu, SS
    Zhou, XZ
    Weng, LH
    ACTA CHIMICA SINICA, 2001, 59 (10) : 1639 - 1645
  • [28] Reactivity of Fe3(CO)9(μ3-C2Et2).: Synthesis and structures of Fe2(CO)6{C2Et2C[CH2N(Me)CH2Ph]CH} and Fe3(CO)8{C2Et2C(H)C[CH2N(Me)CH2Ph]}
    Calderon, R
    Vahrenkamp, H
    JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1998, 555 (01) : 113 - 118
  • [29] THE COORDINATION CHEMISTRY OF IMINOOXOSULFURANES .3. SYNTHESIS OF THE RUTHENIUM COMPLEXES [RU(CO)(PPH3)2(L)(OSNR)] (L=CO, CN-TERT-BU, CNC6H3ME2-2,6 - R=C6H4ME-2, C6H4ME-4)
    HERBERHOLD, M
    HILL, AF
    JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1989, 368 (01) : 111 - 117
  • [30] Synthesis and structural characterization of substituted phenols with a m-terphenyl backbone 2,4,6-R3C6H2OH (R=2,4,6-Me3C6H2, Me5C6)
    Solea, Atena B.
    Olaru, Marian
    Silvestru, Cristian
    Rat, Ciprian I.
    ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, 2015, 70 (01): : 77 - 81
12345