(Me4N)( NO2)(2)C6H3CO2 NEW MCl2 (M = Zn, Co, Cd) AND SnR3Cl (R = Me, Ph) ADDUCTS: SYNTHESIS AND INFRARED STUDY

被引：0

作者：

Traore, Bocar ^{[1
]}

Diop, Libasse ^{[1
]}

Sidibe, Mamadou ^{[1
]}

机构：

[1] Univ Cheikh Anta Diop, Fac Sci & Tech, Dept Chim, Lab Chim Minarale & Analyt LACHIMIA, Dakar, Senegal

来源：

SCIENTIFIC STUDY AND RESEARCH-CHEMISTRY AND CHEMICAL ENGINEERING BIOTECHNOLOGY FOOD INDUSTRY | 2013年 / 14卷 / 02期

关键词：

NO2C6H3CO2](-); ligand; infrared; discrete; structures;

D O I：

暂无

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Five new (Me4N)(NO2)(2)C6H3CO2 adducts with MCl2 (M = Zn, Co, Cd) and SnR3Cl (R = Me, Ph) have been synthesized and studied by infrared spectroscopy. The suggested structures are discrete, the anion behaving as mono-and bichelating ligand towards MX2, tri-and monodentate towards SnR3Cl (R = Me, Ph). The environment around Zn, Co and Cd is tetrahechal, while the tin (IV) centre is trigonal bipyramidal.

引用

页码：119 / 122

页数：4

共 50 条

[1] OS(CO)(4)(ETA(2)-C(2)ME(2))-PROMOTED COUPLING OF ALKYNES AND CO - FORMATION OF (ETA(4)-C(4)ME(2)R(2)CO)OS(CO)(3) (R=ME, ET, PR-N) AND CATALYTIC ACTIVITY OF (ETA(4)-C(4)R(4)CO)OS(CO)(3) (R=ME, PH)
WASHINGTON, J
MCDONALD, R
TAKATS, J
MENASHE, N
RESHEF, D
SHVO, Y
ORGANOMETALLICS, 1995, 14 (08) : 3996 - 4003
[2] N,N'-dimethylurea as a chelating Lewis acid: Synthesis and crystal structures of PPh(4)[Cl(H(2)Me(2)N(2)CO)] and (PPh(4))(2)[Cl(H(2)Me(2)N(2)CO)]Cl
Ghassemzadeh, M
Harms, K
Dehnicke, K
ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, 1996, 51 (10): : 1423 - 1427
[3] Convenient synthesis of K[(C5H4MeMnH(CO)2] and reactions with Cl2B[N(SiMe3)2] and B2R2Cl2 (R = Me2N, Me3C)
Braunschweig, H
Ganter, B
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1997, 545 : 163 - 167
[4] SYNTHESIS AND INFRARED STUDY OF 3(Me4N)(2)MoO4.2SnBr(4) AND (Me4N) 2MoO(4). SnBr4. H2O
Beleke, Alexis Bienvenu
Diop, Libasse
SCIENTIFIC STUDY AND RESEARCH-CHEMISTRY AND CHEMICAL ENGINEERING BIOTECHNOLOGY FOOD INDUSTRY, 2013, 14 (03): : 185 - 188
[5] (Me4N)(2)SO4 circle 4SnPh(3)NCS AND (Me2N)(2)CO circle 4SnPh(3)Cl SYNTHESIS AND SPECTROSCOPIC STUDIES
Okio, Kochikpa A. Y.
Diop, Libasse
SCIENTIFIC STUDY AND RESEARCH-CHEMISTRY AND CHEMICAL ENGINEERING BIOTECHNOLOGY FOOD INDUSTRY, 2010, 11 (04): : 479 - 482
[6] ANIONIC TRIS-DITHIOPHOSPHATO AND TRIS-DITHOPHOSPHINATO COMPLEXES OF ZINC(II) AND COBALT(II) - THE STRUCTURES OF [R4N][M(S2PPH2)3] (M = ZN AND CO, R = ET OR ME) AND OF [ME4N][ZN(S2P(OC6H4ME-P)2)3]
KOWALSKI, RSZ
BAILEY, NA
MULVANEY, R
ADAMS, H
OCLEIRIGH, DA
MCCLEVERTY, JA
TRANSITION METAL CHEMISTRY, 1981, 6 (01) : 64 - 66
[7] SYNTHESES AND CRYSTAL-STRUCTURES OF THE PHOSPHANEIMINE COMPLEXES MCL2(ME3SINPME3)2 WITH M = ZN AND CO, AND COCL2(HNPME3)2
KOCKER, RMZ
FRENZEN, G
NEUMULLER, B
DEHNICKE, K
MAGULL, J
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 1994, 620 (03): : 431 - 437
[8] Synthesis of aryl selenides using arylmercurials. Cyclopalladation of Se(R)Ph [R=C6H3(N=NC(6)H(4)Me-4')-2,Me-5]. Crystal structures of Se(2)R(2) and [Pd{C6H3[N=NC6H3(SePh)-2,Me-4']-2,Me-5}Cl]
Jones, PG
de Arellano, MCR
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1996, (13): : 2713 - 2717
[9] Me4PhPO3H.SnCl4 AND (Me4N)(2)PhPO3. SnBr4: SYNTHESIS AND INFRARED STUDY
Allouch, Hassan
Diop, Libasse
SCIENTIFIC STUDY AND RESEARCH-CHEMISTRY AND CHEMICAL ENGINEERING BIOTECHNOLOGY FOOD INDUSTRY, 2013, 14 (01): : 55 - 58
[10] (Me4N)2O2CSO3Sn(o2CSO3)2 .7Me4NSnCl5: Synthesis and infrared study
Diop, Libasse, 1600, ALMA MATER Publishing House âÇô VASILE ALECSANDRI UNIVERSITY OF BACAU (15):

← 1 2 3 4 5 →