KINETIC AND EQUILIBRIUM ENTHALPY AND ENTROPY TERMS FOR THE OPENING OF AN INTRAMOLECULAR HYDROGEN-BOND IN SOLUTION

被引：0

作者：

CLARKE, MRH ^{[1
]}

HIBBERT, F ^{[1
]}

机构：

[1] UNIV LONDON KINGS COLL,DEPT CHEM,LONDON WC2R 2LS,ENGLAND

来源：

JOURNAL OF CHEMICAL RESEARCH-S | 1991年 / 10期

关键词：

D O I：

暂无

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The temperature dependence of the rate of deprotonation of 2-ethyl-4-(4-nitrophenylazo)resorcinol monoanion in 80% (v/v) Me2SO-H2O in the presence of different concentrations of hydroxide ion has been analysed to give thermodynamic parameters for the equilibrium and kinetics of interconversion between the intramolecularly hydrogen-bonded form of the monoanion and an open non-hydrogen-bonded species.

引用

页码：288 / 289

页数：2

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