KINETIC AND EQUILIBRIUM ENTHALPY AND ENTROPY TERMS FOR THE OPENING OF AN INTRAMOLECULAR HYDROGEN-BOND IN SOLUTION

被引：0
|
作者：
CLARKE, MRH [1 ]
HIBBERT, F [1 ]
机构：
[1] UNIV LONDON KINGS COLL,DEPT CHEM,LONDON WC2R 2LS,ENGLAND
来源：
JOURNAL OF CHEMICAL RESEARCH-S | 1991年 / 10期
关键词：
D O I：
暂无
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The temperature dependence of the rate of deprotonation of 2-ethyl-4-(4-nitrophenylazo)resorcinol monoanion in 80% (v/v) Me2SO-H2O in the presence of different concentrations of hydroxide ion has been analysed to give thermodynamic parameters for the equilibrium and kinetics of interconversion between the intramolecularly hydrogen-bonded form of the monoanion and an open non-hydrogen-bonded species.
引用
收藏
页码：288 / 289
页数：2
相关论文
共 50 条
  • [31] Intramolecular Hydrogen-Bond Activation: Strategies, Benefits, and Influence in Catalysis
    Guerrero-Corella, Andrea
    Fraile, Alberto
    Aleman, Jose
    ACS ORGANIC & INORGANIC AU, 2022, 2 (03): : 197 - 204
  • [32] INTRAMOLECULAR SHORT HYDROGEN-BOND - THE STRUCTURE OF BENZENESULPHONYLHYDRAZONE DERIVATIVE OF SALICYLALDEHYDE
    HUSSAIN, MS
    ALARFAJ, AR
    MAZZAH, A
    JOURNAL OF CHEMICAL CRYSTALLOGRAPHY, 1995, 25 (08) : 511 - 515
  • [33] INTRAMOLECULAR HYDROGEN-BOND AND CHEMICAL-SHIFT OF A BRIDGED PROTON
    LUTSKII, AE
    GORDIENKO, VG
    ZHURNAL OBSHCHEI KHIMII, 1977, 47 (04): : 905 - 910
  • [34] KINETICS AND THERMODYNAMICS OF INTRAMOLECULAR AND INTERMOLECULAR CARBON HYDROGEN-BOND ACTIVATION
    JONES, WD
    FEHER, FJ
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1985, 107 (03) : 620 - 631
  • [35] INTRAMOLECULAR HYDROGEN-BOND AND ELECTROCHEMICAL PROPERTIES OF 2-HYDROXYACETOPHENONES
    STRADYN, YP
    GASANOV, BR
    ISKENDEROVA, TY
    SARDAROVA, SA
    KULIEV, FA
    ZHURNAL OBSHCHEI KHIMII, 1977, 47 (02): : 453 - 460
  • [36] INTRAMOLECULAR HYDROGEN-BOND IN 6-HYDROXY-1-FULVENECARBALDEHYDE
    FUESS, H
    LINDNER, HJ
    CHEMISCHE BERICHTE-RECUEIL, 1975, 108 (09): : 3096 - 3104
  • [37] INTRAMOLECULAR HYDROGEN-BOND ENERGIES .2. THE ETHANOL HALIDES
    SHAGIDULLIN, RR
    PLYAMOVATYI, AK
    BULLETIN OF THE ACADEMY OF SCIENCES OF THE USSR DIVISION OF CHEMICAL SCIENCE, 1981, 30 (03): : 403 - 409
  • [38] POTENTIAL FUNCTION MODEL OF OH ... HALOGEN INTRAMOLECULAR HYDROGEN-BOND
    ROBINSON, EA
    SPENCER, JN
    SCHREIBER, HD
    SPECTROCHIMICA ACTA PART A-MOLECULAR SPECTROSCOPY, 1972, A 28 (03): : 397 - +
  • [39] INTRAMOLECULAR HYDROGEN-BOND IN 1-VINYLPYRAZOLES-5-CARBOXYLATES
    TSERUNYAN, VV
    ASRATYAN, GV
    DARBINYAN, EG
    KHIMIYA GETEROTSIKLICHESKIKH SOEDINENII, 1988, (10): : 1425 - 1425
  • [40] STUDY ON INTRAMOLECULAR HYDROGEN-BOND OF KETONIC AMIDE ESTERS AND AMIDES
    CHIRON, R
    MAISONNE.P
    GRAFF, Y
    COMPTES RENDUS HEBDOMADAIRES DES SEANCES DE L ACADEMIE DES SCIENCES SERIE C, 1973, 276 (01): : 105 - 108
12345