ONE-POT PREPARATION OF 3-METHYLENEPYRROLIDINES WITH HIGH DIASTEREOMERIC EXCESS

被引：11
|
作者：
VANDERHEIDE, TAJ [1 ]
VANDERBAAN, JL [1 ]
DEKIMPE, V [1 ]
BICKELHAUPT, F [1 ]
KLUMPP, GW [1 ]
机构：
[1] FREE UNIV AMSTERDAM,SCHEIKUNDIG LAB,DE BOELELAAN 1083,1081 HV AMSTERDAM,NETHERLANDS
来源：
TETRAHEDRON LETTERS | 1993年 / 34卷 / 20期
关键词：
BIFUNCTIONAL ANNULATION REAGENT; ALLYLZINC COMPOUNDS; PD(0)-CATALYSIS; PROLINE; HETEROCYCLIC RING SYNTHESIS;
D O I：
10.1016/S0040-4039(00)73690-2
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Addition of allylzinc reagents 1 to imines carrying a carbalkoxy group at C-alpha or C-alpha', followed by Pd(0)-catalyzed cyclization permits the one-pot preparation of 3-methylenepyrrolidines with high diastereoselectivity.
引用
收藏
页码：3309 / 3310
页数：2
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