Oxidation of Condensed Thiophene Derivatives with Brønsted Acidic Ionic Liquid

被引：0
|
作者：
A. V. Akopyan
E. A. Eseva
P. D. Polikarpova
A. A. Kedalo
A. V. Anisimov
机构：
[1] Moscow State University,
来源：
Moscow University Chemistry Bulletin | 2019年 / 74卷
关键词：
ionic liquid; Brønsted acid center; molybdenum-containing catalysts; hydrogen peroxide; oxidative desulfurization;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
Abstract—A catalyst based on ionic liquid consisting of a pyridinium cation having Brønsted acidity and a molybdenum anion (1-butyl-3-carboxypyridinium molybdate) is obtained. Its catalytic activity in the oxidation of sulfur-containing compounds is studied. The influence of the oxidation’s duration, temperature, and the quantity of the oxidation agent and catalyst on the conversion of dibenzothiophene (DBT) is also considered. The conversion of DBT is 100% in the presence of the catalyst under the following conditions: molar ratio H2O2 : S = 10 : 1, catalyst mass 0.02 g, reaction temperature 50°C, and duration 120 min.
引用
收藏
页码：284 / 289
页数：5
相关论文
共 50 条
  • [41] Surfactant-like Brønsted acidic ionic liquid as an efficient catalyst for selective Mannich reaction and biodiesel production in water
    Majid Vafaeezadeh
    Mina Karbalaie-Reza
    Mohammad Mahmoodi Hashemi
    Kasra Qasempour Soleimany
    Journal of the Iranian Chemical Society, 2017, 14 : 907 - 914
  • [42] Brønsted Acidic Ionic Liquid: An Efficient Organocatalyst for the Synthesis of Pyrrolo[1,2-a]indoles under Neat Conditions
    Pramanik, Tanmay
    Pal, Satyajit
    Santra, Sougata
    Majee, Adinath
    SYNLETT, 2024, 35 (20) : 2447 - 2452
  • [43] Functionalized Brønsted-Lewis acidic ionic liquid as an efficient catalyst for synthesis of 1-amidoalkyl-2-naphthols
    Mei, Lai-Bao (meilb@njtech.edu.cn), 2016, Fine Chemicals (33):
  • [44] Highly efficient solvent-free synthesis of pyranopyrazoles by a Brønsted-acidic ionic liquid as a green and reusable catalyst
    JAVAD EBRAHIMI
    ALI MOHAMMADI
    VAHID PAKJOO
    EHSAN BAHRAMZADE
    AMIR HABIBI
    Journal of Chemical Sciences, 2012, 124 : 1013 - 1017
  • [45] Knoevenagel Condensation Catalyzed by DBU Brnsted Ionic Liquid without Solvent
    YING An-guo1
    2. Xinchang Pharmaceuticals Factory
    ChemicalResearchinChineseUniversities, 2009, 25 (06) : 876 - 881
  • [46] Mannich reaction in water phase catalyzed by new Brønsted acidic functionalized ionic liquids
    Fang, Dong
    Liu, Zuliang
    Nanjing Hangkong Hangtian Daxue Xuebao/Journal of Nanjing University of Aeronautics and Astronautics, 2007, 39 (04): : 540 - 543
  • [47] Brønsted acidic ionic liquids catalyze the preparation of 2,3-dihydroquinazolin-4(1H)-one derivatives
    Hamid Reza Shaterian
    Morteza Aghakhanizadeh
    Research on Chemical Intermediates, 2014, 40 : 1655 - 1668
  • [48] Transesterification of palm oil to biodiesel using Br?nsted acidic ionic liquid as high-efficient and eco-friendly catalyst
    Yaoyao Feng
    Ting Qiu
    Jinbei Yang
    Ling Li
    Xiaoda Wang
    Hongxing Wang
    ChineseJournalofChemicalEngineering, 2017, 25 (09) : 1222 - 1229
  • [49] Brønsted-acidic ionic liquid supported nanomagnetic: a novel and reusable catalyst for synthesis of oxygen-containing heterocyclic compounds
    Masoomeh Norouzi
    Maryam Khanmoradi
    Research on Chemical Intermediates, 2023, 49 : 4785 - 4804
  • [50] Facile Preparation of β-Cyclodextrin-Fe3O4 Magnetic-Brønsted Acidic Ionic Liquid for Biodiesel Production
    Fei Chang
    Quan Zhou
    Waste and Biomass Valorization, 2020, 11 : 1983 - 1988
12345