Molten state and solvent-free systems studied by NMR spectroscopy: addition reactions catalyzed by transition metal complexes

被引：0
|
作者：
V. P. Ananikov
I. P. Beletskaya
机构：
[1] Russian Academy of Sciences,N. D. Zelinsky Institute of Organic Chemistry
[2] M. V. Lomonosov Moscow State University,Department of Chemistry
来源：
Russian Chemical Bulletin | 2008年 / 57卷
关键词：
NMR spectroscopy; solvent-free reactions; molten state reactions; transition metal catalysis; alkynes;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
In the present review we address scarcely studied application area of NMR spectroscopy — investigation of molten state and solvent-free systems. In such a case NMR spectra are recorded without a solvent and without magnetic field stabilization on any nucleus. Taking our recent studies of catalytic addition of sulfur- and selenium-containing compounds to alkynes as examples, we describe most important practical aspects of NMR studies and their application for solving important chemical problems.
引用
收藏
页码：754 / 760
页数：6
相关论文
共 42 条
  • [41] Water oxidation by Bronsted acid-catalyzed in situ generated thiol cation: dual function of the acid catalyst leading to transition metal-free substitution and addition reactions of S-S bonds
    Ma, Xiantao
    Zhu, Yingying
    Yu, Jing
    Yan, Ran
    Xie, Xiaoni
    Huang, Lijun
    Wang, Qi
    Chang, Xue-Ping
    Xu, Qing
    ORGANIC CHEMISTRY FRONTIERS, 2022, 9 (12) : 3204 - 3214
  • [42] NMR RELAXATION STUDIES IN SOLUTION OF TRANSITION-METAL COMPLEXES .5. PROTON-EXCHANGE REACTIONS IN AQUEOUS-SOLUTIONS OF VO2+-OXALIC ACID, VO2+-MALONIC ACID SYSTEMS
    NAGYPAL, I
    FABIAN, I
    INORGANICA CHIMICA ACTA-ARTICLES, 1982, 61 (01): : 109 - 113
12345