Molten state and solvent-free systems studied by NMR spectroscopy: addition reactions catalyzed by transition metal complexes

被引:0
|
作者
V. P. Ananikov
I. P. Beletskaya
机构
[1] Russian Academy of Sciences,N. D. Zelinsky Institute of Organic Chemistry
[2] M. V. Lomonosov Moscow State University,Department of Chemistry
来源
Russian Chemical Bulletin | 2008年 / 57卷
关键词
NMR spectroscopy; solvent-free reactions; molten state reactions; transition metal catalysis; alkynes;
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中图分类号
学科分类号
摘要
In the present review we address scarcely studied application area of NMR spectroscopy — investigation of molten state and solvent-free systems. In such a case NMR spectra are recorded without a solvent and without magnetic field stabilization on any nucleus. Taking our recent studies of catalytic addition of sulfur- and selenium-containing compounds to alkynes as examples, we describe most important practical aspects of NMR studies and their application for solving important chemical problems.
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页码:754 / 760
页数:6
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