Molten state and solvent-free systems studied by NMR spectroscopy: addition reactions catalyzed by transition metal complexes

被引：0
|
作者：
V. P. Ananikov
I. P. Beletskaya
机构：
[1] Russian Academy of Sciences,N. D. Zelinsky Institute of Organic Chemistry
[2] M. V. Lomonosov Moscow State University,Department of Chemistry
来源：
Russian Chemical Bulletin | 2008年 / 57卷
关键词：
NMR spectroscopy; solvent-free reactions; molten state reactions; transition metal catalysis; alkynes;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
In the present review we address scarcely studied application area of NMR spectroscopy — investigation of molten state and solvent-free systems. In such a case NMR spectra are recorded without a solvent and without magnetic field stabilization on any nucleus. Taking our recent studies of catalytic addition of sulfur- and selenium-containing compounds to alkynes as examples, we describe most important practical aspects of NMR studies and their application for solving important chemical problems.
引用
收藏
页码：754 / 760
页数：6
相关论文
共 42 条
  • [1] Molten state and solvent-free systems studied by NMR spectroscopy: addition reactions catalyzed by transition metal complexes
    Ananikov, V. P.
    Beletskaya, I. P.
    RUSSIAN CHEMICAL BULLETIN, 2008, 57 (04) : 754 - 760
  • [2] Substitution and addition reactions catalyzed by transition metal complexes
    Beletskaya, IP
    PERSPECTIVES IN ORGANOMETALLIC CHEMISTRY, 2003, (287): : 240 - 252
  • [3] KOtBu-Catalyzed Michael Addition Reactions Under Mild and Solvent-Free Conditions
    Thiyagarajan, Subramanian
    Krishnakumar, Varadhan
    Gunanathan, Chidambaram
    CHEMISTRY-AN ASIAN JOURNAL, 2020, 15 (04) : 518 - 523
  • [4] Mechanism of the solvent-free reactions between indole derivatives and 4-nitrobenzaldehyde studied by solid-state NMR and DFT calculations
    Chierotti, Michele R.
    Gaglioti, Katia
    Gobetto, Roberto
    Barbero, Margherita
    Nervi, Carlo
    CRYSTENGCOMM, 2012, 14 (20) : 6732 - 6737
  • [5] Asymmetric direct aldol reactions catalyzed by chiral amine macrocycle-metal(II) complexes under solvent-free conditions
    Tanaka, Koichi
    Asakura, Azusa
    Muraoka, Toshihide
    Kalicki, Przemyslaw
    Urbanczyk-Lipkowska, Zofia
    NEW JOURNAL OF CHEMISTRY, 2013, 37 (09) : 2851 - 2855
  • [6] Investigating metal catalyzed reactions under solvent-free high speed ball milling (HSBM) conditions
    Cook, Teresa L.
    Mack, James
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2012, 244
  • [7] Complementarity of Solvent-Free MALDI TOF and Solid-State NMR Spectroscopy in Spectral Analysis of Polylactides
    Sroka-Bartnicka, Anna
    Ciesielskl, Wlodzimierz
    Libiszowski, Jan
    Duda, Andrzej
    Sochacki, Marek
    Potrzebowski, Marek J.
    ANALYTICAL CHEMISTRY, 2010, 82 (01) : 323 - 328
  • [8] Efficient solvent-free fixation of CO2 catalyzed by new recyclable bifunctional metal complexes
    Peng, Jing
    Yang, Hai-Jian
    Wang, Sheng
    Ban, Binru
    Wei, Zidong
    Lei, Bo
    Guo, Cun-Yue
    JOURNAL OF CO2 UTILIZATION, 2018, 24 : 1 - 9
  • [9] Solvent-free isomerization of methyl chavicol to trans-anethole using transition metal complexes as catalysts
    Sharma, SK
    Srivastava, VK
    Pandya, PH
    Jasra, RV
    CATALYSIS COMMUNICATIONS, 2005, 6 (03) : 205 - 209
  • [10] Acid-catalyzed intramolecular oxa-Michael addition reactions under solvent-free and microwave irradiation conditions
    Hong, Yi-Ming
    Shen, Zhen-Lu
    Hu, Xin-Quan
    Mo, Wei-Min
    He, Xiao-Fei
    Hu, Bao-Xiang
    Sun, Nan
    ARKIVOC, 2009, : 146 - 155
12345