Enantioconvergent synthesis of P-stereogenic allenylphosphines

被引：0
|
作者：
机构：
来源：
Nature Synthesis | 2022年 / 1卷
关键词：
D O I：
暂无
中图分类号：
学科分类号：
摘要：
A strategy to synthesize allenylphosphine derivatives with both P and axial chirality is developed and allows for diverse derivatizations of chiral phosphines. The Ni-catalysed enantioconvergent reaction occurs without racemization or symmetrization of the propargylic carbonate substrate, as demonstrated by combined experimental and computational methods.
引用
收藏
页码：680 / 681
页数：1
相关论文
共 50 条
  • [31] P-stereogenic ligands in enantioselective catalysis
    Grabulosa, Arnald
    RSC Catalysis Series, 2010, : 1 - 521
  • [32] Accelerated and Enantioselective Synthesis of a Library of P-Stereogenic Urea Phosphines
    Koshti, Vijay S.
    Gote, Ravindra P.
    Chikkali, Samir H.
    EUROPEAN JOURNAL OF ORGANIC CHEMISTRY, 2018, 2018 (47) : 6768 - 6779
  • [33] General synthesis of P-stereogenic compounds: the menthyl phosphinate approach
    Berger, Olivier
    Montchamp, Jean-Luc
    ORGANIC & BIOMOLECULAR CHEMISTRY, 2016, 14 (31) : 7552 - 7562
  • [34] Asymmetric Synthesis of P-Stereogenic Secondary Phosphine Oxides (SPOs)
    Glueck, David S.
    SYNTHESIS-STUTTGART, 2022, 54 (02): : 271 - 280
  • [35] Catalytic Asymmetric Synthesis of P-Stereogenic Phosphines: Beyond Precious Metals
    Glueck, David S.
    SYNLETT, 2021, 32 (09) : 875 - 884
  • [36] Synthesis of C3-symmetric P-stereogenic triphosphine ligands
    Cain, Matthew F.
    Hughes, Russell P.
    Glueck, David S.
    Golen, James A.
    Rheingold, Arnold L.
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2011, 242
  • [37] Synthesis and Alkali-Metal-Ion Complexation of P-Stereogenic Diphosphacrowns
    Morisaki, Yasuhiro
    Kato, Ryosuke
    Chujo, Yoshiki
    CHEMISTRYOPEN, 2016, 5 (04): : 325 - 330
  • [38] Asymmetric Synthesis of Prodrug Nucleotides (ProTides): Construction of the P-Stereogenic Centers
    Liu, Yichen
    Cheng, Jiefei
    Hong, Ran
    CHINESE JOURNAL OF ORGANIC CHEMISTRY, 2020, 40 (10) : 3237 - 3248
  • [39] Experimental and Theoretical Investigations of the Stereoselective Synthesis of P-Stereogenic Phosphine Oxides
    Copey, Laurent
    Jean-Gerard, Ludivine
    Framery, Eric
    Pilet, Guillaume
    Robert, Vincent
    Andrioletti, Bruno
    CHEMISTRY-A EUROPEAN JOURNAL, 2015, 21 (25) : 9057 - 9061
  • [40] Stereoselective Synthesis of P-Stereogenic Aminophosphines: Ring Opening of Bulky Oxazaphospholidines
    Leon, Thierry
    Riera, Antoni
    Verdaguer, Xavier
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2011, 133 (15) : 5740 - 5743
12345