Synthesis and crystal structure of new one-dimensional copper(II) complex [Cu4(En)2(μ1,1-N3)4(μ1,1,1-N3)2(μ1,3-N3)2]n

被引：0
|
作者：
A. D. Khalaji
H. Stoeckli-Evans
机构：
[1] Golestan University,Department of Chemistry, Faculty of Science
[2] University of Neuchatel,Institute of Physics, Laboratory Physical Chemistry
来源：
Russian Journal of Coordination Chemistry | 2011年 / 37卷
关键词：
Azido; Apical Plane; Tetranuclear Cluster; Azido Ligand; Azido Bridge;
D O I：
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学科分类号：
摘要：
A new polymer azido-bridged copper(II) complex [Cu4(En)2(μ1,1-N3)4(μ1,1,1-N3)2(μ1,3-N3)2]n (I) (En = ethylenediamine) has been synthesized and crystallography characterized. Complex I shows one-dimensional coordination polymeric structure based on a tetranuclear cluster unit [Cu4(En)2(μ1,1-N3)4(μ1,1,1-N3)2(μ1,3-N3)2], in which the azido ions display three different bridging modes.
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页码：535 / 540
页数：5
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