Electronic structure and magnetic properties of clusters with (μ-1,1-N3) bridges

被引：0
|
作者：
Rakitin, YV [1 ]
Khodasevich, SG [1 ]
Starodub, OR [1 ]
Kalinnikov, VT [1 ]
机构：
[1] Russian Acad Sci, Kola Res Ctr, Inst Rare Element & Mineral Chem & Technol, Apatity 184200, Murmansk Oblast, Russia
来源：
RUSSIAN JOURNAL OF COORDINATION CHEMISTRY | 2001年 / 27卷 / 01期
基金：
俄罗斯基础研究基金会;
关键词：
D O I：
10.1023/A:1009592621701
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Quantum-chemical calculations and a generalized angular overlap model were used to demonstrate that the electronic structure of N-3(-) anions is favorable for the development of ferromagnetic properties in poly-nuclear complexes whose structural elements are planar binuclear fragments of the M(N-3)(2)M type characterized by a broad range of M-N-M angles (95 degrees -105 degrees). Analysis of the known experimental data points to the correctness of the theoretical views and demonstrates the ferromagnetic stability of complexes of this type to the deviation of the N-3 ligands from the plane of the MN2M ring.
引用
收藏
页码：1 / 4
页数：4
相关论文
共 50 条
  • [1] Electronic Structure and Magnetic Properties of Clusters with (μ-1,1-N3) Bridges
    Yu. V. Rakitin
    S. G. Khodasevich
    O. R. Starodub
    V. T. Kalinnikov
    Russian Journal of Coordination Chemistry, 2001, 27 : 1 - 4
  • [2] A novel tetranuclear copper(II) complex with alternating μ1,1-azido and phenoxo bridges:: Synthesis, structure, and magnetic properties of [Cu4(μ-salen)2(μ1,1-N3)2(N3)2]
    Koner, S
    Saha, S
    Okamoto, KI
    Tuchagues, JP
    INORGANIC CHEMISTRY, 2003, 42 (15) : 4668 - 4672
  • [3] Binuclear μ1,1-N3 and O-H•••O bridged nickel(II) complex with a N3O chelating agent:: Synthesis, structure and magnetic properties
    Sarkar, Sumana
    Mondal, Amrita
    Banerjee, Atanu
    Chopra, Deepak
    Ribas, Joan
    Rajak, Kajal Krishna
    POLYHEDRON, 2006, 25 (11) : 2284 - 2288
  • [4] Structure, stability, and electronic and magnetic properties of small RhnMn (n = 1–12) clusters
    Ru Shan
    Ling Suo
    Jin Lv
    Hai-Shun Wu
    The European Physical Journal D, 2018, 72
  • [5] Structure, Stability, and Electronic and Magnetic Properties of VGen (n=1-19) Clusters
    Siouani, C.
    Mahtout, S.
    Safer, S.
    Rabilloud, F.
    JOURNAL OF PHYSICAL CHEMISTRY A, 2017, 121 (18): : 3540 - 3554
  • [6] Structure and magnetic behaviour of a novel alternating one-dimensional chain compound {[Cu(phen)(μ1,1-N3)]2(μ-ta)}n
    Li, LC
    Liao, DZ
    Jiang, ZH
    Yan, SP
    POLYHEDRON, 2001, 20 (7-8) : 681 - 684
  • [7] Synthesis, characterization and crystal structure of tetranuclear copper(II) complex [Cu4(μ-Salophen)2(μ1,1-N3)2(N3)2] with alternating μ1,1-azido and phenoxo bridges
    A. D. Khalaji
    S. Triki
    Russian Journal of Coordination Chemistry, 2012, 38 : 579 - 582
  • [8] Synthesis, X-ray structure, spectroscopic and magnetic properties of [Cu(DACO)( μ-1,1-N3)μ-1,3-N3)]n and [Cu(DACO)( μ-NCS)(NCS)]n (DACO=1,5-diazacyclooctane)
    Wang, ZD
    Han, W
    Bian, F
    Liu, ZQ
    Yan, SP
    Liao, DZ
    Jiang, ZH
    Cheng, P
    JOURNAL OF MOLECULAR STRUCTURE, 2005, 733 (1-3) : 125 - 131
  • [9] Synthesis, characterization and crystal structure of tetranuclear copper(II) complex [Cu4(μ-Salophen)2(μ1,1-N3)2(N3)2] with alternating μ1,1-azido and phenoxo bridges
    Khalaji, A. D.
    Triki, S.
    RUSSIAN JOURNAL OF COORDINATION CHEMISTRY, 2012, 38 (08) : 579 - 582
  • [10] Equilibrium geometries, electronic structure, and magnetic properties of NinSn clusters (n=1-12)
    Deshpande, M. D.
    Roy, Swapna
    Kanhere, D. G.
    PHYSICAL REVIEW B, 2007, 76 (19)
12345