Electrochemical synthesis of tris(2-chloroethyl) phosphate

被引：0
|
作者：
M. Yu. Berezkin
V. V. Turygin
A. P. Tomilov
机构：
[1] State Research Institute of Organic Chemistry and Technology,
来源：
Russian Journal of Electrochemistry | 2015年 / 51卷
关键词：
trialkyl phosphates; tris(2-chloroethyl) phosphate; alcohols; ethylene chlorohydrin; white phosphorus; red phosphorus; electrochemical synthesis;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
Process of preparation of tris(2-chloroethyl) phosphate, a neutral ester of ethylene chlorohydrin and phosphoric acid, by direct electrochemical synthesis from elemental phosphorus and ethylene chlorohydrin in a diaphragmless electrolyzer was studied. Solubility of white phosphorus in tris(2-chloroethyl) phosphate was studied. The formation of tris(2-chloroethyl) phosphate from white and red phosphorus was found to proceed in close yields.
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页码：1086 / 1091
页数：5
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