Electrochemical synthesis of tris(2-chloroethyl) phosphate

被引：0
|
作者：
M. Yu. Berezkin
V. V. Turygin
A. P. Tomilov
机构：
[1] State Research Institute of Organic Chemistry and Technology,
来源：
Russian Journal of Electrochemistry | 2015年 / 51卷
关键词：
trialkyl phosphates; tris(2-chloroethyl) phosphate; alcohols; ethylene chlorohydrin; white phosphorus; red phosphorus; electrochemical synthesis;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
Process of preparation of tris(2-chloroethyl) phosphate, a neutral ester of ethylene chlorohydrin and phosphoric acid, by direct electrochemical synthesis from elemental phosphorus and ethylene chlorohydrin in a diaphragmless electrolyzer was studied. Solubility of white phosphorus in tris(2-chloroethyl) phosphate was studied. The formation of tris(2-chloroethyl) phosphate from white and red phosphorus was found to proceed in close yields.
引用
收藏
页码：1086 / 1091
页数：5
相关论文
共 50 条
  • [31] Tris(2-chloroethyl)phosphate increases ambulatory activity in mice: Pharmacological analyses of its neurochemical mechanism
    Umezu, T
    Yonemoto, J
    Soma, Y
    Suzuki, T
    TOXICOLOGY AND APPLIED PHARMACOLOGY, 1998, 148 (01) : 109 - 116
  • [32] Rhizobiales as the Key Member in the Synergistic Tris (2-chloroethyl) Phosphate (TCEP) Degradation by Two Bacterial Consortia
    Liang, Yi
    Zhou, Xiangyu
    Wu, Yiding
    Wu, Yang
    Gao, Shutao
    Zeng, Xiangying
    Yu, Zhiqiang
    WATER RESEARCH, 2022, 218
  • [33] Effects of tris (2-chloroethyl) phosphate (TCEP) on growth, reproduction and gene transcription in the protozoan Tetrahymena thermophila
    Hao, Hui
    Yuan, Siliang
    Cheng, Shiyang
    Sun, Qian
    Giesy, John P.
    Liu, Chunsheng
    AQUATIC TOXICOLOGY, 2020, 222
  • [34] TiO2 Photocatalytic degradation of the flame retardant, tris (2-chloroethyl) phosphate: Kinetic and mechanistic studies
    Abdullah, A. M.
    O'Shea, Kevin
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2017, 253
  • [35] The underestimated environmental risk of tris (2-chloroethyl) phosphate photodegradation in aqueous environment induced by polystyrene microplastics
    Wu, Nannan
    Yu, Haibin
    Liu, Zhenzhen
    Di, Shanshan
    Zhao, Huiyu
    Wang, Zhiwei
    Wang, Zunyao
    Wang, Xinquan
    Qi, Peipei
    WATER RESEARCH, 2025, 273
  • [36] Synthesis of di(2-chloroethyl) formal
    Gubaidullin, LY
    Chugunov, YV
    Ioffe, DS
    Gubaidullin, IL
    Tyutko, KA
    Fazlyeva, MG
    Minigulov, FG
    RUSSIAN JOURNAL OF APPLIED CHEMISTRY, 1996, 69 (01) : 153 - 154
  • [37] Investigations of toxic effects of the flame retardants tris-(2-chloroethyl)-phosphate (TCEP) and tris-(2-chloro propyl)-phosphate (TCPP) in vitro
    Föllmann, W
    Spiteller, M
    Degen, GH
    Vollmer, G
    Bester, K
    NAUNYN-SCHMIEDEBERGS ARCHIVES OF PHARMACOLOGY, 2004, 369 : R145 - R145
  • [38] SUBCHRONIC TOXICITY STUDIES INDICATE THAT TRIS(2-CHLOROETHYL)PHOSPHATE ADMINISTRATION RESULTS IN LESIONS IN THE RAT HIPPOCAMPUS
    MATTHEWS, HB
    DIXON, D
    HERR, DW
    TILSON, H
    TOXICOLOGY AND INDUSTRIAL HEALTH, 1990, 6 (01) : 1 - 15
  • [39] Effects of tris(2-chloroethyl) phosphate exposure on chicken embryos in a shell-less incubation system
    Kanda, Kazuki
    Ito, Shohei
    Koh, Dong-Hee
    Kim, Eun-Young
    Iwata, Hisato
    ECOTOXICOLOGY AND ENVIRONMENTAL SAFETY, 2021, 207
  • [40] Degradation of tris(2-chloroethyl) phosphate (TCEP) by thermally activated persulfate: Combination of experimental and theoretical study
    Liu, He
    Liang, Jiahao
    Du, Xiaodong
    Wang, Rui
    Tang, Ting
    Tao, Xueqin
    Yin, Hua
    Dang, Zhi
    Lu, Guining
    SCIENCE OF THE TOTAL ENVIRONMENT, 2022, 809
12345