Transesterification and compatibilization in the blends of bisphenol-A polycarbonate and poly(trimethylene terephthalate)

被引:0
|
作者
Sang-Kuwon Na
Byeong-Gi Kong
Changyong Choi
Mi-Kyeong Jang
Jae-Woon Nah
Jung-Gyu Kim
Byung-Wook Jo
机构
[1] Sunchon National University,Department of Polymer Science and Engineering
[2] Chosun University,Chemical and Polymer Science & Engineering
来源
Macromolecular Research | 2005年 / 13卷
关键词
poly(trimethylene terephthalate); polycarbonate; blend; transesterification; compatibilization;
D O I
暂无
中图分类号
学科分类号
摘要
Melt blending of Bisphenol A polycarbonate(PC) and poly(trimethylene terephthalate)(PTT) was carried out over the entire composition range. The mixing time was varied up to 90 min. The resulting samples were analyzed by FT-IR, DSC, XRD, DMTA,1H NMR, and SEM. The process of transesterification between the two polymers and their resulting compatibilization were observed. The behaviors of the PTT-rich and PC-rich blends were different and an equilibrium was found to exist. Peculiar behavior, which was different from that of the PTT-rich and PC-rich blends, was exhibited by the 50/50(PTT/PC) blend.
引用
收藏
页码:88 / 95
页数:7
相关论文
共 50 条
  • [31] BISPHENOL-A POLYCARBONATE-POLY(BUTYLENE TEREPHTHALATE) TRANSESTERIFICATION - 3. STUDY OF MODEL REACTIONS.
    DEVAUX, J.
    GODARD, P.
    MERCIER, J.P.
    1982, V 20 (N 10): : 1895 - 1900
  • [32] MOLTEN BISPHENOL-A POLYCARBONATE-POLY(ETHYLENE TEREPHTHALATE) BLENDS .1. IDENTIFICATION OF THE REACTIONS
    GODARD, P
    DEKONINCK, JM
    DEVLESAVER, V
    DEVAUX, J
    JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 1986, 24 (12) : 3301 - 3313
  • [33] MISCIBLE BLENDS OF POLY(BUTYLENE TEREPHTHALATE) AND THE POLYHYDROXYETHER OF BISPHENOL-A
    ROBESON, LM
    FURTEK, AB
    JOURNAL OF APPLIED POLYMER SCIENCE, 1979, 23 (03) : 645 - 659
  • [34] Influence of chain structure on phase Behavior and thermal degradation of poly(trimethylene terephthalate)/poly(hydroxy ether) of bisphenol-A blends
    Farmahini-Farahani, Madjid
    Jafari, Seyed Hassan
    Khonakdar, Hossein Ali
    Yavari, Ahmad
    Bakhshi, Raheleh
    Tarameshlou, Mohammad
    MACROMOLECULAR MATERIALS AND ENGINEERING, 2007, 292 (10-11) : 1103 - 1110
  • [35] Compatibilization of poly(trimethylene terephthalate)/polycarbonate blends by epoxy. Part 2. Melting behavior and spherulite morphology
    Xue, ML
    Yu, YL
    Sheng, J
    Chuah, HH
    Geng, CH
    JOURNAL OF MACROMOLECULAR SCIENCE-PHYSICS, 2005, B44 (03): : 331 - 343
  • [36] BISPHENOL-A POLYCARBONATE-POLY(BUTYLENE TEREPHTHALATE) TRANSESTERIFICATION - 4. KINETICS AND MECHANISM OF THE EXCHANGE REACTION.
    DEVAUX, J.
    GODARD, P.
    MERCIER, J.P.
    1982, V 20 (N 10): : 1901 - 1907
  • [37] Structures and properties of ternary blends of recycled poly(ethylene terephthalate)/bisphenol-A polycarbonate/(E/nBA/GMA)
    Peng, Yong
    Guo, Weihong
    Zhu, Ping
    Wu, Chifei
    JOURNAL OF APPLIED POLYMER SCIENCE, 2008, 109 (01) : 483 - 491
  • [38] Crystallization and Spherulitic Growth Kinetics of Poly(trimethylene terephthalate)/Polycarbonate Blends
    El Shafee, Ez
    Naguib, Halle F.
    Li, Longfei
    Jiang, Shichun
    An, Lijia
    POLYMER ENGINEERING AND SCIENCE, 2010, 50 (05): : 1036 - 1046
  • [39] Enthalpy relaxation in bisphenol-A polycarbonate/poly(methyl methacrylate) blends
    Penco, Maurizio
    Sartore, Luciana
    Della Sciucca, Stefania
    POLYMER ENGINEERING AND SCIENCE, 2007, 47 (03): : 218 - 224
  • [40] Isothermal Crystallization Kinetics of Tricomponent Blends of Polycarbonate, Poly(Trimethylene Terephthalate) and Polybutylene Terephthalate
    Al-Mulla, Adam
    Al-Omairi, Lafi
    Mathew, Johnson
    Bhattacharya, Sathi
    POLYMERS & POLYMER COMPOSITES, 2010, 18 (06): : 245 - 251