Transesterification and compatibilization in the blends of bisphenol-A polycarbonate and poly(trimethylene terephthalate)

被引:0
|
作者
Sang-Kuwon Na
Byeong-Gi Kong
Changyong Choi
Mi-Kyeong Jang
Jae-Woon Nah
Jung-Gyu Kim
Byung-Wook Jo
机构
[1] Sunchon National University,Department of Polymer Science and Engineering
[2] Chosun University,Chemical and Polymer Science & Engineering
来源
Macromolecular Research | 2005年 / 13卷
关键词
poly(trimethylene terephthalate); polycarbonate; blend; transesterification; compatibilization;
D O I
暂无
中图分类号
学科分类号
摘要
Melt blending of Bisphenol A polycarbonate(PC) and poly(trimethylene terephthalate)(PTT) was carried out over the entire composition range. The mixing time was varied up to 90 min. The resulting samples were analyzed by FT-IR, DSC, XRD, DMTA,1H NMR, and SEM. The process of transesterification between the two polymers and their resulting compatibilization were observed. The behaviors of the PTT-rich and PC-rich blends were different and an equilibrium was found to exist. Peculiar behavior, which was different from that of the PTT-rich and PC-rich blends, was exhibited by the 50/50(PTT/PC) blend.
引用
收藏
页码:88 / 95
页数:7
相关论文
共 50 条
  • [21] BISPHENOL A POLYCARBONATE AND POLY(BUTYLENE TEREPHTHALATE) BLENDS
    WASICKI, A
    MAJERSKA, B
    PRZEMYSL CHEMICZNY, 1995, 74 (01): : 15 - 18
  • [22] Compatibilization of poly(trimethylene terephthalate)/polycarbonate blends by epoxy. Part 1. Miscibility and morphology
    Xue, ML
    Yu, YL
    Sheng, J
    Chuah, HH
    Geng, CH
    JOURNAL OF MACROMOLECULAR SCIENCE-PHYSICS, 2005, B44 (03): : 317 - 329
  • [23] Compatibilizing effect of transesterification product between components in bisphenol-A polycarbonate/poly(ethylene terephthalate) blend
    Ma, DZ
    Zhang, GY
    He, YY
    Ma, JW
    Lio, XL
    JOURNAL OF POLYMER SCIENCE PART B-POLYMER PHYSICS, 1999, 37 (21) : 2960 - 2972
  • [24] Influence of Polycarbonate on the Crystallization Behavior of Poly(Trimethylene Terephthalate)/Polycarbonate Blends
    Xue, Meiling
    Lu, Xiangzhou
    Yu, Xinyu
    Chen, Zian
    Wang, Jiangong
    Li, Zhen
    JOURNAL OF MACROMOLECULAR SCIENCE PART B-PHYSICS, 2019, 58 (03): : 452 - 468
  • [25] MISCIBILITY AND TRANS-ESTERIFICATION IN BISPHENOL-A POLYCARBONATE POLY(ETHYLENE-TEREPHTHALATE) BLENDS
    SUZUKI, T
    TANAKA, H
    NISHI, T
    POLYMER, 1989, 30 (07) : 1287 - 1297
  • [26] Morphology of High-Pressure Crystallized Poly (ethylene terephthalate)/Bisphenol-A Polycarbonate Blends
    Lu, Jun
    Zhang, Daopeng
    Tian, Jiaojiao
    Huang, Rui
    ADVANCED MATERIALS RESEARCH, 2011, 213 : 470 - +
  • [27] Blends of aromatic polysulphones and alkene terephthalate polymers: Compatibilization with polyhydroxyether of bisphenol-A
    Mascia, L
    Martin, LH
    HIGH PERFORMANCE POLYMERS, 1996, 8 (01) : 119 - 131
  • [28] Calorimetric and dielectric study on poly(trimethylene terephthalate)/polycarbonate blends
    El Shafee, E.
    Saad, G. R.
    Zaki, M.
    JOURNAL OF POLYMER RESEARCH, 2008, 15 (01) : 47 - 58
  • [29] PHOTODEGRADATION OF POLY(METHYL METHACRYLATE) BISPHENOL-A POLYCARBONATE BLENDS
    GUERRERO, AR
    RAMIREZ, JC
    POLYMER BULLETIN, 1994, 33 (05) : 541 - 548
  • [30] Calorimetric and dielectric study on poly(trimethylene terephthalate)/polycarbonate blends
    E. El Shafee
    G. R. Saad
    M. Zaki
    Journal of Polymer Research, 2008, 15 : 47 - 58