Iodination of B12H11OC(O)CH2–3, B12H11OH2–, and B12H11SCN2–

被引：0
|
作者：
L. V. Gorobinskii
A. S. Chernyavskii
K. A. Solntsev
N. T. Kuznetsov
机构：
[1] Russian Academy of Sciences,Kurnakov Institute of General and Inorganic Chemistry
来源：
Russian Journal of Coordination Chemistry | 2001年 / 27卷
关键词：
Physical Chemistry; Benzene; Carboxy; Iodo; Thiocyanato;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
Reactions of iodination of monosubstituted derivatives of B12H11X2–anion (X = OC(O)CH3, OH, SCN) were studied. The reactions were shown to proceed smoothly to give B12H10(OC(O)CH3)I2–((carboxy)(iodo)[decahydro[Ih1551-Δ20-closo]dodecaborate(2–)] anion), B12H10(OH)I2–((hydroxo)(iodo)[decahydro[Ih1551-Δ20-closo]dodecaborate(2–)] anion), and B12H10(SCN)I2–((thiocyanato)(iodo)[decahydro[Ih1551-Δ20-closo]dodecaborate(2–)] anion) in high yields, irrespective of the solvent used (benzene, H2O–ROH, where R = C2H5, CH2CH2CH3).1
引用
收藏
页码：147 / 149
页数：2
相关论文
共 50 条
  • [31] Anionic oligomerization of Li2[B12H12] and Li[CB11H12]: An experimental and computational study
    Dávalos, J.Z. (jdavalos@iqfr.csic.es), 1600, American Chemical Society (117):
  • [32] Anionic Oligomerization of Li2[B12H12] and Li[CB11H12]: An Experimental and Computational Study
    Davalos, Juan Z.
    Gonzalez, Javier
    Guerrero, Andres
    Hnyk, Drahomir
    Holub, Josef
    Oliva, Josep M.
    JOURNAL OF PHYSICAL CHEMISTRY C, 2013, 117 (03): : 1495 - 1501
  • [33] Crystal structure of [MnII (1,10-C12H8N2)3]2+[(B9C2H11)CoIII(B8C2H10)CoIII(B9C2H11)]2−·CH3CN
    T. M. Polyanskaya
    V. V. Volkov
    M. K. Drozdova
    Journal of Structural Chemistry, 2005, 46 : 708 - 718
  • [34] An addition to the oxoacid family:: H2B12(OH)12
    Stasko, DJ
    Perzynski, KJ
    Wasil, MA
    Brodbeck, JK
    Kirschbaum, K
    Kim, YW
    Lind, C
    INORGANIC CHEMISTRY, 2004, 43 (13) : 3786 - 3788
  • [35] A new method for the preparation of Na2B12H11SH from thiourea derivative B12H11SC(NH2)2- via electrochemical synthesis of the latter
    Brattsev, VA
    Morris, JH
    ADVANCES IN NEUTRON CAPTURE THERAPY, VOLS I AND II: VOL I: MEDICINE AND PHYSICS, VOL II: CHEMISTRY AND BIOLOGY, 1997, 1132 : B51 - B55
  • [36] Rb2[B12(OH)12]•2H2O and Rb2[B12(OH)12]•2H2O2: Hydrate and perhydrolate of rubidium dodecahydroxo-closo-dodecaborate
    Schoelkopf, Thomas
    Nguyen-Duc Van
    Schleid, Thomas
    INORGANICA CHIMICA ACTA, 2011, 374 (01) : 181 - 186
  • [37] Theoretical study of 11B NMR chemical shifts of prototypical boranes: The case of closo-[B12H12]2-, nest-B11H15, and arachno-B10H16
    Morales-Bayuelo, A.
    Catalan Lavin, J. M.
    Ramirez-Tagle, R.
    INDIAN JOURNAL OF CHEMISTRY SECTION A-INORGANIC BIO-INORGANIC PHYSICAL THEORETICAL & ANALYTICAL CHEMISTRY, 2018, 57 (02): : 143 - 149
  • [38] PREPARATION AND NUCLEAR MAGNETIC-RESONANCE STUDIES OF STEREOCHEMICALLY NONRIGID ANIONS B4H9-, B5H12-, B6H11-, AND B7H12-. IMPROVED SYNTHESES OF B5H11 AND B6H12
    REMMEL, RJ
    JOHNSON, HD
    JAWORIWSKY, IS
    SHORE, SG
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1975, 97 (19) : 5395 - 5403
  • [39] 1-B9H9CH- AND B11H11CH-
    KNOTH, WH
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1967, 89 (05) : 1274 - &
  • [40] REARRANGEMENT MECHANISMS OF B12H12(2-) AND C2B10H12
    WALES, DJ
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1993, 115 (04) : 1557 - 1567
12345