Iodination of B12H11OC(O)CH2–3, B12H11OH2–, and B12H11SCN2–

被引：0
|
作者：
L. V. Gorobinskii
A. S. Chernyavskii
K. A. Solntsev
N. T. Kuznetsov
机构：
[1] Russian Academy of Sciences,Kurnakov Institute of General and Inorganic Chemistry
来源：
Russian Journal of Coordination Chemistry | 2001年 / 27卷
关键词：
Physical Chemistry; Benzene; Carboxy; Iodo; Thiocyanato;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
Reactions of iodination of monosubstituted derivatives of B12H11X2–anion (X = OC(O)CH3, OH, SCN) were studied. The reactions were shown to proceed smoothly to give B12H10(OC(O)CH3)I2–((carboxy)(iodo)[decahydro[Ih1551-Δ20-closo]dodecaborate(2–)] anion), B12H10(OH)I2–((hydroxo)(iodo)[decahydro[Ih1551-Δ20-closo]dodecaborate(2–)] anion), and B12H10(SCN)I2–((thiocyanato)(iodo)[decahydro[Ih1551-Δ20-closo]dodecaborate(2–)] anion) in high yields, irrespective of the solvent used (benzene, H2O–ROH, where R = C2H5, CH2CH2CH3).1
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页码：147 / 149
页数：2
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