Iodination of B12H11OC(O)CH2–3, B12H11OH2–, and B12H11SCN2–

被引：0

作者：

L. V. Gorobinskii

A. S. Chernyavskii

K. A. Solntsev

N. T. Kuznetsov

机构：

[1] Russian Academy of Sciences,Kurnakov Institute of General and Inorganic Chemistry

来源：

Russian Journal of Coordination Chemistry | 2001年 / 27卷

关键词：

Physical Chemistry; Benzene; Carboxy; Iodo; Thiocyanato;

D O I：

暂无

中图分类号：

学科分类号：

摘要：

Reactions of iodination of monosubstituted derivatives of B12H11X2–anion (X = OC(O)CH3, OH, SCN) were studied. The reactions were shown to proceed smoothly to give B12H10(OC(O)CH3)I2–((carboxy)(iodo)[decahydro[Ih1551-Δ20-closo]dodecaborate(2–)] anion), B12H10(OH)I2–((hydroxo)(iodo)[decahydro[Ih1551-Δ20-closo]dodecaborate(2–)] anion), and B12H10(SCN)I2–((thiocyanato)(iodo)[decahydro[Ih1551-Δ20-closo]dodecaborate(2–)] anion) in high yields, irrespective of the solvent used (benzene, H2O–ROH, where R = C2H5, CH2CH2CH3).1

引用

页码：147 / 149

页数：2

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