Chloromethylation of Bis(2-thienyl) Sulfide

被引：0
|
作者：
L. K. Papernaya
E. N. Sukhomazova
E. P. Levanova
G. F. Myachina
E. N. Deryagina
机构：
[1] Russian Academy of Sciences,Favorskii Irkutsk Institute of Chemistry, Siberian Division
来源：
Russian Journal of Organic Chemistry | 2002年 / 38卷
关键词：
Polymer; Sulfur; Methylene; Sulfide; Electric Conductivity;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
Chloromethylation of bis(2-thienyl) sulfide is accompanied by fast polycondensation of the primary chloromethylation product with the initial sulfide. The reaction gives a new polymer in which the thiophene rings are alternately separated by sulfur atoms and methylene groups. Fusion of the polymer with molecular sulfur gave new sulfur-enriched polymers whose specific electric conductivity is comparable with that of organic semiconductors.
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页码：1495 / 1497
页数：2
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