Chloromethylation of Bis(2-thienyl) Sulfide

被引:0
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作者
L. K. Papernaya
E. N. Sukhomazova
E. P. Levanova
G. F. Myachina
E. N. Deryagina
机构
[1] Russian Academy of Sciences,Favorskii Irkutsk Institute of Chemistry, Siberian Division
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Polymer; Sulfur; Methylene; Sulfide; Electric Conductivity;
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摘要
Chloromethylation of bis(2-thienyl) sulfide is accompanied by fast polycondensation of the primary chloromethylation product with the initial sulfide. The reaction gives a new polymer in which the thiophene rings are alternately separated by sulfur atoms and methylene groups. Fusion of the polymer with molecular sulfur gave new sulfur-enriched polymers whose specific electric conductivity is comparable with that of organic semiconductors.
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页码:1495 / 1497
页数:2
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