Thiazole-Flanked Thiazoloisoindigo as a Monomer for Balanced Ambipolar Polymeric Field-effect Transistors

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作者
Si-Yu Lv
Qi-Yi Li
Bo-Wen Li
Jie-Yu Wang
You-Bing Mu
Liang Li
Jian Pei
Xiao-Bo Wan
机构
[1] Jianghan University,Key Laboratory of Optoelectronic Chemical Materials and Devices, Ministry of Education, School of Optoelectronic Materials & Technology
[2] Peking University,Beijing National Laboratory for Molecular Sciences, the Key Laboratory of Bioorganic Chemistry and Molecular Engineering of Ministry of Education, College of Chemistry and Molecular Engineering
[3] Wuhan Institute of Technology,School of Materials Science and Engineering
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关键词
Thiazoloisoindigo; Ambipolar; Polymeric field-effect transistors;
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摘要
Electron-rich thiophene-flanked thiazoloisoindigo (Th-TzII) has been reported as a building block for ambipolar polymeric field-effect transistors however with preferable hole transport. Here, we report that by using an electron deficient thiazole as the flanked moiety, the corresponding thiazoloisoindigo (Tz-TzII) can still be synthesized, although in a more sinuous way. Theoretical calculation and experimental results demonstrate that Tz-TzII is more electron-deficient than Th-TzII, and the corresponding polymer P(TzII-Tz-T-Tz) exhibits high and balanced hole/electron mobility of 0.70/0.64 cm2·V−1·s−1.
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页码:1131 / 1140
页数:9
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