Catalytic brdicka-type systems in alternating-current square-wave voltammetry

被引：0
|
作者：
V. I. Gorokhovskaya
机构：
[1] Kazan State Technological University,Department of Chemistry and Petroleum Chemistry
来源：
Journal of Analytical Chemistry | 2000年 / 55卷
关键词：
Cobalt; Cystine; Catalytic System; Indicator System; Peak Height Ratio;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
Conventional kinetic and adsorption parameters of signals detected by alternating-current squarewave voltammetry in the catalytic systems cobalt(II)-NH3-cysteine (cystine) and nickel(II)-NH3-cysteine (cystine) in the presence of excess catalyst (metal ions) were discussed. The parameters for the optimization of the detected signals (mercury column height and mercury dropping rate) were considered. The characteristics of the cobalt(II)-NH3-cystine-containing protein indicator system were qualitatively compared with those of the model cobalt(H)-NH3-cystine system.
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页码：358 / 362
页数：4
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