2,2-Bis(methoxy- and ethoxy-NNO-azoxy)propane-1,3-diol sulfonates

被引:0
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作者
I. N. Zyuzin
机构
[1] Russian Academy of Sciences,Institute of Problems of Chemical Physics
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关键词
Diol; Colorless Crystal; Sulfonyl Chloride; Anhydrous Acetonitrile; Sulfonic Ester;
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摘要
2,2-Bis(alkoxy-NNO-azoxy)propane-1,3-diols react with sulfonyl chlorides and trifluoromethanesulfonic anhydride in the presence of bases affording previously unknown methane-, trifluoromethane-, benzene and toluenesulfonates (sulfonic esters) of 2-bis(methoxy- and ethoxy-NNO-azoxy)propane-1,3-diols. The triflates are thermally less stable than mesylates, benzenesulfonates, and tosylates of the corresponding diols.
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页码:631 / 634
页数:3
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