2,2-Bis(methoxy- and ethoxy-NNO-azoxy)propane-1,3-diol sulfonates

被引：0
|
作者：
I. N. Zyuzin
机构：
[1] Russian Academy of Sciences,Institute of Problems of Chemical Physics
来源：
Russian Journal of Organic Chemistry | 2014年 / 50卷
关键词：
Diol; Colorless Crystal; Sulfonyl Chloride; Anhydrous Acetonitrile; Sulfonic Ester;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
2,2-Bis(alkoxy-NNO-azoxy)propane-1,3-diols react with sulfonyl chlorides and trifluoromethanesulfonic anhydride in the presence of bases affording previously unknown methane-, trifluoromethane-, benzene and toluenesulfonates (sulfonic esters) of 2-bis(methoxy- and ethoxy-NNO-azoxy)propane-1,3-diols. The triflates are thermally less stable than mesylates, benzenesulfonates, and tosylates of the corresponding diols.
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页码：631 / 634
页数：3
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