Carbon 1s binding energy and substituent effects in C-centered radical cations

被引：0
|
作者：
A. N. Egorochkin
M. G. Voronkov
O. V. Kuznetsova
O. V. Novikova
N. M. Khamaletdinova
机构：
[1] Russian Academy of Sciences,G. A. Razuvaev Institute of Organometallic Chemistry
[2] Siberian Branch of the Russian Academy of Sciences,A. E. Favorsky Institute of Chemistry
来源：
Russian Chemical Bulletin | 2009年 / 58卷
关键词：
carbon 1s binding energy; inductive effect; conjugation; polarizability effect of substituents;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
The carbon 1s binding energies (Eb) measured by X-ray photoelectron spectroscopy or obtained from quantum chemical calculations for 18 series of compounds in which the reaction center is the C atom are analyzed. It was established for the first time that Eb values in carboncentered radical cations depend on the inductive, resonance, and polarizability effects of substituents.
引用
收藏
页码：1562 / 1568
页数：6
相关论文
共 50 条
  • [41] The substituent effect of the methyl group.: Carbon 1s ionization energies, proton affinities, and reactivities of the methylbenzenes
    Myrseth, Velaug
    Saethre, Leif J.
    Borve, Knut J.
    Thomas, T. Darrah
    JOURNAL OF ORGANIC CHEMISTRY, 2007, 72 (15): : 5715 - 5723
  • [42] OXYGEN (1S) BINDING-ENERGIES IN CARBON-MONOXIDE ADSORPTION ON METALS
    JOYNER, RW
    ROBERTS, MW
    CHEMICAL PHYSICS LETTERS, 1974, 29 (03) : 447 - 448
  • [43] Low kinetic energy photoelectron diffractions for C 1s and O 1s electrons of free CO molecules in the EXAFS region
    Adachi, Jun-ichi
    Yamazaki, Masakazu
    Kazama, Misato
    Ohori, Yusuke
    Teramoto, Takahiro
    Kimura, Yasuyuki
    Yagishita, Akira
    Fujikawa, Takashi
    14TH INTERNATIONAL CONFERENCE ON X-RAY ABSORPTION FINE STRUCTURE (XAFS14), PROCEEDINGS, 2009, 190
  • [44] Carbon speciation in airborne particulate matter with C (1s) NEXAFS spectroscopy
    Braun, A
    JOURNAL OF ENVIRONMENTAL MONITORING, 2005, 7 (11): : 1059 - 1065
  • [45] Vibrationally resolved C and O 1s photoelectron spectra of carbon dioxide
    Hatamoto, T.
    Matsumoto, M.
    Liu, X-J
    Ueda, K.
    Hoshino, M.
    Nakagawa, K.
    Tanaka, T.
    Tanaka, H.
    Ehara, M.
    Tamaki, R.
    Nakatsuji, H.
    JOURNAL OF ELECTRON SPECTROSCOPY AND RELATED PHENOMENA, 2007, 155 (1-3) : 54 - 57
  • [46] Vibrationally resolved C and O 1s photoelectron spectra of carbon monoxides
    Matsumoto, M
    Ueda, K
    Kukk, E
    Yoshida, H
    Tanaka, T
    Kitajima, M
    Tanaka, H
    Tamenori, Y
    Kuramoto, K
    Ehara, A
    Nakatsuji, H
    CHEMICAL PHYSICS LETTERS, 2006, 417 (1-3) : 89 - 93
  • [47] Matrix effects in the C 1s photoabsorption spectra of condensed naphthalene
    Schmidt, Norman
    Wenzel, Jan
    Dreuw, Andreas
    Fink, Rainer H.
    Hieringer, Wolfgang
    JOURNAL OF CHEMICAL PHYSICS, 2016, 145 (23):
  • [48] Persistent 2c-3e σ-bonded heteronuclear radical cations centered on S/Se and P/As atoms
    Yang, Wenbang
    Wang, Wenqing
    Zhang, Leran
    Zhang, Li
    Ruan, Huapeng
    Feng, Zhongtao
    Fang, Yong
    Wang, Xinping
    CHEMICAL COMMUNICATIONS, 2021, 57 (41) : 5067 - 5070
  • [49] XPS C 1s binding energies for fluorocarbon-hydrocarbon microblock copolymers
    Lei, YG
    Ng, KM
    Weng, LT
    Chan, CM
    Li, L
    SURFACE AND INTERFACE ANALYSIS, 2003, 35 (10) : 852 - 855
  • [50] On the application of a modified Sanderson formalism to atomic charge-C 1s binding energy correlation in some aromatic molecules
    Materials Chemistry Division, National Chemical Laboratory, Pune, 411 008, India
    J Electron Spectrosc Relat Phenom, 3 (249-256):
12345