Carbon 1s binding energy and substituent effects in C-centered radical cations

被引：0
|
作者：
A. N. Egorochkin
M. G. Voronkov
O. V. Kuznetsova
O. V. Novikova
N. M. Khamaletdinova
机构：
[1] Russian Academy of Sciences,G. A. Razuvaev Institute of Organometallic Chemistry
[2] Siberian Branch of the Russian Academy of Sciences,A. E. Favorsky Institute of Chemistry
来源：
Russian Chemical Bulletin | 2009年 / 58卷
关键词：
carbon 1s binding energy; inductive effect; conjugation; polarizability effect of substituents;
D O I：
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中图分类号：
学科分类号：
摘要：
The carbon 1s binding energies (Eb) measured by X-ray photoelectron spectroscopy or obtained from quantum chemical calculations for 18 series of compounds in which the reaction center is the C atom are analyzed. It was established for the first time that Eb values in carboncentered radical cations depend on the inductive, resonance, and polarizability effects of substituents.
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页码：1562 / 1568
页数：6
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