Complexation of 1-hexadecyl-4-aza-1-azoniabicyclo[2.2.2]octane bromide with nickel nitrate in acetone

被引：0
|
作者：
E. P. Zhiltsova
S. S. Lukashenko
M. R. Ibatullina
M. P. Kutyreva
L. Ya. Zakharova
机构：
[1] Russian Academy of Sciences,Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center
[2] Kazan Federal University,undefined
来源：
Russian Journal of Physical Chemistry A | 2016年 / 90卷
关键词：
alkylated derivative of cyclic diamine 1,4-diazabicyclo[2.2.2]octane (DABCO); transition metals; complexation; complex stability constant;
D O I：
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中图分类号：
学科分类号：
摘要：
The complexation of 1-hexadecyl-4-aza-1-azoniabicyclo[2.2.2]octane bromide with Ni(II) nitrate in acetone is studied by means of spectrophotometry (the Job–Ostromisslensky technique and molar ratios). The formation of 3: 1 and 1: 1 ligand: metal complexes is established and confirmed by mathematical modeling. The stability constants of the complexes and the change in the Gibbs free energy are determined.
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页码：1374 / 1378
页数：4
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