Complexes of 1-alkyl-4-aza-1-azoniabicyclo[2.2.2]octane bromides with lanthanum nitrate. Micelle-forming and adsorption properties

被引：6
|
作者：
Zhil'tsova, E. P. [1 ]
Ibatullina, M. R. [1 ]
Lukashenko, S. S. [1 ]
Kutyreva, M. P. [2 ]
Anuar, M. M. [1 ]
Kovalenko, V. I. [1 ]
Zakharova, L. Ya. [1 ]
机构：
[1] Russian Acad Sci, Arbuzov Inst Organ & Phys Chem, Kazan Res Ctr, Ul Akad Arbuzova 8, Kazan 420088, Tatarstan, Russia
[2] Kazan Volga Reg Fed Univ, Butlerov Inst Chem, Kazan, Tatarstan, Russia
来源：
RUSSIAN JOURNAL OF GENERAL CHEMISTRY | 2017年 / 87卷 / 11期
基金：
俄罗斯基础研究基金会;
关键词：
monoquaternized 1,4-diazabicyclo[2.2.2]octane; complex; surfactant; aggregation; adsorption; AGGREGATION BEHAVIOR; CATALYTIC-PROPERTIES; AQUEOUS-MEDIUM; SURFACTANTS; MICELLIZATION; BINARY; AMPHIPHILES; MIXTURES; AGENTS;
D O I：
10.1134/S1070363217110172
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Novel organometallic surfactants were synthesized from monoquaternized 1,4-diazabicyclo[2.2.2]-octanes of varied hydrophobicity [Alk = C (n) H2n+1, n = 14, 18] and lanthanum nitrates. The spectral, micelleforming, and adsorption properties of the synthesized compounds were studied by IR, (1)De NMR and electronic spectroscopy, tensiometry, conductometry, and potentiometry. The critical micelle concentrations, counterionic micellar binding constants, and adsorption parameters at the water-air interface were determined and compared with the respective characteristics of the ligands and conventional amphiphiles.
引用
收藏
页码：2620 / 2626
页数：7
相关论文
共 50 条
  • [1] Complexes of 1-alkyl-4-aza-1-azoniabicyclo[2.2.2]octane bromides with lanthanum nitrate. Micelle-forming and adsorption properties
    E. P. Zhil’tsova
    M. R. Ibatullina
    S. S. Lukashenko
    M. P. Kutyreva
    M. M. Anuar
    V. I. Kovalenko
    L. Ya. Zakharova
    Russian Journal of General Chemistry, 2017, 87 : 2620 - 2626
  • [2] Complexes of 1-alkyl-4-aza-1-azoniabicyclo[2.2.2]octane bromides with lanthanum nitrate: Aggregation and interaction with biomolecules
    Zhiltsova, Elena P.
    Ibatullina, Marina R.
    Kuznetsova, Darya A.
    Gabdrakhmanov, Dinar R.
    Lukashenko, Svetlana S.
    Voloshina, Alexandra D.
    Sapunova, Anastasiia S.
    Lenina, Oksana A.
    Faizullin, Dzhigangir A.
    Zuev, Yuriy F.
    Zakharova, Lucia Ya
    JOURNAL OF MOLECULAR LIQUIDS, 2021, 340
  • [3] Catalytic Systems Based on the Metal Complexes of 1-Alkyl-4-Aza-1-Azoniabicyclo[2.2.2]Octane Bromides
    E. P. Zhil’tsova
    M. R. Ibatullina
    S. S. Lukashenko
    I. R. Nizameev
    M. K. Kadirov
    L. Ya. Zakharova
    Kinetics and Catalysis, 2020, 61 : 269 - 275
  • [4] Supramolecular systems based on 1-alkyl-4-aza-1-azoniabicyclo[2.2.2]octane bromides
    T. N. Pashirova
    E. P. Zhil’tsova
    R. R. Kashapov
    S. S. Lukashenko
    A. I. Litvinov
    M. K. Kadirov
    L. Ya. Zakharova
    A. I. Konovalov
    Russian Chemical Bulletin, 2010, 59 : 1745 - 1752
  • [5] Catalytic Systems Based on the Metal Complexes of 1-Alkyl-4-Aza-1-Azoniabicyclo[2.2.2]Octane Bromides
    Zhil'tsova, E. P.
    Ibatullina, M. R.
    Lukashenko, S. S.
    Nizameev, I. R.
    Kadirov, M. K.
    Zakharova, L. Ya.
    KINETICS AND CATALYSIS, 2020, 61 (02) : 269 - 275
  • [6] Supramolecular systems based on 1-alkyl-4-aza-1-azoniabicyclo[2.2.2]octane bromides
    Pashirova, T. N.
    Zhil'tsova, E. P.
    Kashapov, R. R.
    Lukashenko, S. S.
    Litvinov, A. I.
    Kadirov, M. K.
    Zakharova, L. Ya.
    Konovalov, A. I.
    RUSSIAN CHEMICAL BULLETIN, 2010, 59 (09) : 1745 - 1752
  • [7] COMPLEXATION OF 1-ALKYL-4-AZA-1-AZONIABICYCLO[2.2.2] OCTANE BROMIDES WITH TRANSITION METAL CATIONS IN ACETONE
    Zhil'tsova, E. P.
    Ibatullina, M. R.
    Lukashenko, S. S.
    Pashirova, T. N.
    Kutyreva, M. P.
    Zakharova, L. Ya.
    LIQUID CRYSTALS AND THEIR APPLICATION, 2015, 15 (04): : 48 - 55
  • [8] Complexes of 1-hexadecyl-4-aza-1-azoniabicyclo[2.2.2]octane bromide with transition metal nitrates. Micelle-forming, solubilizing, and adsorption properties
    E. P. Zhiltsova
    M. R. Ibatullina
    S. S. Lukashenko
    F. G. Valeeva
    T. N. Pashirova
    M. P. Kutyreva
    L. Ya. Zakharova
    Colloid Journal, 2017, 79 : 621 - 629
  • [9] Complexes of 1-hexadecyl-4-aza-1-azoniabicyclo[2.2.2]octane bromide with transition metal nitrates. Micelle-forming, solubilizing, and adsorption properties
    Zhiltsova, E. P.
    Ibatullina, M. R.
    Lukashenko, S. S.
    Valeeva, F. G.
    Pashirova, T. N.
    Kutyreva, M. P.
    Zakharova, L. Ya.
    COLLOID JOURNAL, 2017, 79 (05) : 621 - 629
  • [10] Krafft Temperature of 1-Alkyl-4-Aza-1-Azoniabicyclo[2.2.2]octane Bromide Complexes with Transition Metal Salts
    Ibatullina, M. R.
    Zhil'tsova, E. P.
    Lukashenko, S. S.
    Anuar, M. M.
    Kutyreva, M. P.
    Zakharova, L. Ya.
    RUSSIAN JOURNAL OF PHYSICAL CHEMISTRY A, 2018, 92 (04) : 799 - 803
12345