Electronic structure of monosubstituted benzenes and X-ray emission spectroscopy3. Fluorobenzene

被引：0
|
作者：
V. D. Yumatov
A. V. Okotrub
G. G. Furin
N. F. Salakhutdinov
机构：
[1] Siberian Branch of the Russian Academy of Sciences,Institute of Inorganic Chemistry
[2] Siberian Branch of the Russian Academy of Sciences,Novosibirsk Institute of Organic Chemistry
来源：
Russian Chemical Bulletin | 1997年 / 46卷
关键词：
X-ray emission; F−Kα spectra and C−Kα spectra; MNDO; fluorobenzene;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
The electronic structure of fluorobenzene was investigated by X-ray emission spectroscopy (using the F−Kα- and C−Kα-spectra) and quantum-chemical MNDO calculations. Molecular orbitals of fluorobenzene were compared with those of benzene and hydrogen fluoride. The Pπ−pπ-interaction between the phenyl ring and the fluorine atom in the fluorobenzene molecule is weak for both the outer and inner π levels.
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页码：1389 / 1395
页数：6
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