Electronic structure of monosubstituted benzenes and X-ray emission spectroscopy3. Fluorobenzene

被引：0
|
作者：
V. D. Yumatov
A. V. Okotrub
G. G. Furin
N. F. Salakhutdinov
机构：
[1] Siberian Branch of the Russian Academy of Sciences,Institute of Inorganic Chemistry
[2] Siberian Branch of the Russian Academy of Sciences,Novosibirsk Institute of Organic Chemistry
来源：
Russian Chemical Bulletin | 1997年 / 46卷
关键词：
X-ray emission; F−Kα spectra and C−Kα spectra; MNDO; fluorobenzene;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
The electronic structure of fluorobenzene was investigated by X-ray emission spectroscopy (using the F−Kα- and C−Kα-spectra) and quantum-chemical MNDO calculations. Molecular orbitals of fluorobenzene were compared with those of benzene and hydrogen fluoride. The Pπ−pπ-interaction between the phenyl ring and the fluorine atom in the fluorobenzene molecule is weak for both the outer and inner π levels.
引用
收藏
页码：1389 / 1395
页数：6
相关论文
共 50 条
  • [21] X-ray emission spectroscopy and theoretical study of the electronic structure of hexamethyldisiloxane and octamethylcyclotetrasiloxane
    T. N. Danilenko
    M. M. Tatevosyan
    V. G. Vlasenko
    Russian Journal of General Chemistry, 2017, 87 : 923 - 928
  • [22] Electronic Structure of Hemin in Solution Studied by Resonant X-ray Emission Spectroscopy and Electronic Structure Calculations
    Atak, Kaan
    Golnak, Ronny
    Xiao, Jie
    Suljoti, Edlira
    Pflueger, Mika
    Brandenburg, Tim
    Winter, Bernd
    Aziz, Emad F.
    JOURNAL OF PHYSICAL CHEMISTRY B, 2014, 118 (33): : 9938 - 9943
  • [23] Electronic structure of BP studied by resonant soft X-ray emission spectroscopy
    Agui, A
    Shin, S
    Kumashiro, Y
    JOURNAL OF THE PHYSICAL SOCIETY OF JAPAN, 1999, 68 (01) : 166 - 169
  • [24] Modern soft X-ray emission spectroscopy - A new look on electronic structure
    Nordgren, EJ
    PHYSICA SCRIPTA, 1996, T61 : 32 - 37
  • [25] Electronic structure of NPB and BCP molecules probed by x-ray emission spectroscopy
    Seo, J. H.
    Kim, C. Y.
    Kang, S. J.
    Yoo, K. -H.
    Whang, C. N.
    Moewes, A.
    Chang, G. S.
    JOURNAL OF CHEMICAL PHYSICS, 2007, 126 (06):
  • [26] X-Ray Emission Spectroscopy and Theoretical Study of the Electronic Structure of Hexamethyldisiloxane and Octamethylcyclotetrasiloxane
    Danilenko, T. N.
    Tatevosyan, M. M.
    Vlasenko, V. G.
    RUSSIAN JOURNAL OF GENERAL CHEMISTRY, 2017, 87 (05) : 923 - 928
  • [27] Modern soft X-ray emission spectroscopy - a new look on electronic structure
    Nordgren, E.Joseph
    Physica Scripta T, 1996, T61 : 32 - 37
  • [28] Electronic structure of FeSi1-xGex and FeGa3 investigated by soft x-ray photoelectron spectroscopy complementary to x-ray emission spectroscopy
    Yamaoka, H.
    Matsunami, M.
    Eguchi, R.
    Ishida, Y.
    Tsujii, N.
    Takahashi, Y.
    Senba, Y.
    Ohashi, H.
    Shin, S.
    PHYSICAL REVIEW B, 2008, 78 (04):
  • [29] Electronic Structure of the Hieber Anion [Fe(Co)3(NO)]- Revisited by X-ray Emission and Absorption Spectroscopy
    Burkhardt, Lukas
    Vukadinovic, Yannik
    Nowakowski, Michal
    Kalinko, Aleksandr
    Rudolph, Julian
    Carlsson, Per-Anders
    Jacob, Christoph R.
    Bauer, Matthias
    INORGANIC CHEMISTRY, 2020, 59 (06) : 3551 - 3561
  • [30] X-RAY PHOTOELECTRON SPECTROSCOPY OF FLUORINATED BENZENES
    DAVIS, DW
    THOMAS, TD
    SHIRLEY, DA
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1972, 94 (19) : 6565 - &
12345