Hexahydro-8-isoquinolones with electron-acceptor substituents in position 4

被引：0

作者：

Ozols Ya. ^{[1
]}

Vigante B. ^{[1
]}

Baumane L. ^{[1
]}

Mishnev A. ^{[1
]}

Turovskis I. ^{[1
]}

Duburs G. ^{[1
]}

Stradyn' Ya. ^{[1
]}

机构：

[1] Latvian Institute of Organic Synthesis

来源：

Chemistry of Heterocyclic Compounds | 1998年 / 34卷 / 10期

关键词：

Oxidation; Organic Chemistry; Diffraction Analysis; Nitro Group; Structural Effect;

D O I：

10.1007/BF02319495

中图分类号：

学科分类号：

摘要：

By the interaction of 2-acetyl-5,5-dimethyl-2-cyclohexen-1-one with certain nitroenamines, a number of hexahydro-8-isoquinolones with a nitro group in position 4 have been obtained; potentials of their electrochemical oxidation have been determined, and a possible mechanism and manifestation of structural effects in this process have been suggested and discussed. The structure of 1,3,6,6-tetramethyl-4-nitro-2,4a,-5,6,7,8-hexahydro-8-isoquinolone has been established by means of x-ray diffraction analysis. ©1999 Kluwer Academic/Plenum Publishers.

引用

页码：1166 / 1173

页数：7

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