Hexahydro-8-isoquinolones with electron-acceptor substituents in position 4

被引：0
|
作者：
Ozols Ya. [1 ]
Vigante B. [1 ]
Baumane L. [1 ]
Mishnev A. [1 ]
Turovskis I. [1 ]
Duburs G. [1 ]
Stradyn' Ya. [1 ]
机构：
[1] Latvian Institute of Organic Synthesis
来源：
Chemistry of Heterocyclic Compounds | 1998年 / 34卷 / 10期
关键词：
Oxidation; Organic Chemistry; Diffraction Analysis; Nitro Group; Structural Effect;
D O I：
10.1007/BF02319495
中图分类号：
学科分类号：
摘要：
By the interaction of 2-acetyl-5,5-dimethyl-2-cyclohexen-1-one with certain nitroenamines, a number of hexahydro-8-isoquinolones with a nitro group in position 4 have been obtained; potentials of their electrochemical oxidation have been determined, and a possible mechanism and manifestation of structural effects in this process have been suggested and discussed. The structure of 1,3,6,6-tetramethyl-4-nitro-2,4a,-5,6,7,8-hexahydro-8-isoquinolone has been established by means of x-ray diffraction analysis. ©1999 Kluwer Academic/Plenum Publishers.
引用
收藏
页码：1166 / 1173
页数：7
相关论文
共 50 条
12345