Photodecomposition of chromium tricarbonyl complexes with styrene, stilbene, and 1,4-diphenylbuta-1,3-diene in solution

被引:0
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作者
O. G. Mishchenko
S. V. Klement’eva
S. V. Maslennikov
A. N. Artemov
I. V. Spirina
机构
[1] Lobachevskii Nizhnii Novgorod State University,Research Institute of Chemistry
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关键词
Styrene; Quantum Yield; General Chemistry; Stilbene; Tricarbonyl;
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摘要
Photolytic decomposition of styrene, stilbene, and 1,4-diphenylbuta-1,3-diene tricarbonyl chromium complexes in solution results in elimination of the carbonyl ligands and formation of binuclear alkenylarene chromium complexes. The quantum yields and activation and kinetic parameters of these processes were determined, and a scheme was proposed to rationalize photoinitiated transformations of the organochromium compounds under study.
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页码:1907 / 1910
页数:3
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