Photodecomposition of chromium tricarbonyl complexes with styrene, stilbene, and 1,4-diphenylbuta-1,3-diene in solution

被引：0

作者：

O. G. Mishchenko

S. V. Klement’eva

S. V. Maslennikov

A. N. Artemov

I. V. Spirina

机构：

[1] Lobachevskii Nizhnii Novgorod State University,Research Institute of Chemistry

来源：

Russian Journal of General Chemistry | 2006年 / 76卷

关键词：

Styrene; Quantum Yield; General Chemistry; Stilbene; Tricarbonyl;

D O I：

暂无

中图分类号：

学科分类号：

摘要：

Photolytic decomposition of styrene, stilbene, and 1,4-diphenylbuta-1,3-diene tricarbonyl chromium complexes in solution results in elimination of the carbonyl ligands and formation of binuclear alkenylarene chromium complexes. The quantum yields and activation and kinetic parameters of these processes were determined, and a scheme was proposed to rationalize photoinitiated transformations of the organochromium compounds under study.

引用

页码：1907 / 1910

页数：3

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