Oxidation and reductive bromination of Bis(4-tert-butylphenyl)aminoxyl

被引：0
|
作者：
V. A. Golubev
V. D. Sen’
机构：
[1] Russian Academy of Sciences,Institute of Problems of Chemical Physics
来源：
Russian Journal of Organic Chemistry | 2013年 / 49卷
关键词：
MeCN; Bromine Atom; Tribromide; Oxoammonium; Aminyl;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
One-electron oxidation of bis(4-tert-butylphenyl)aminoxyl with antimony pentachloride and bromine leads to the formation of oxoammonium salts with anions SbCl6− and Br3− respectively. The salt with the Br3− anion converted at heating into a mixture of bromodiphenylamines which formed also from the aminoxyl as a result of previously unknown reaction of three-electron reductive bromination. The mechanisms of these reactions were assumed.
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页码：1143 / 1149
页数：6
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