Oxidation and reductive bromination of Bis(4-tert-butylphenyl)aminoxyl

被引：0

作者：

V. A. Golubev

V. D. Sen’

机构：

[1] Russian Academy of Sciences,Institute of Problems of Chemical Physics

来源：

Russian Journal of Organic Chemistry | 2013年 / 49卷

关键词：

MeCN; Bromine Atom; Tribromide; Oxoammonium; Aminyl;

D O I：

暂无

中图分类号：

学科分类号：

摘要：

One-electron oxidation of bis(4-tert-butylphenyl)aminoxyl with antimony pentachloride and bromine leads to the formation of oxoammonium salts with anions SbCl6− and Br3− respectively. The salt with the Br3− anion converted at heating into a mixture of bromodiphenylamines which formed also from the aminoxyl as a result of previously unknown reaction of three-electron reductive bromination. The mechanisms of these reactions were assumed.

引用

页码：1143 / 1149

页数：6

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