Reductive bromination of N, N-bis(4-tert-butylphenyl)hydroxylamine

被引:0
|
作者
V. A. Golubev
Yu. D. Kim
机构
[1] Russian Academy of Sciences,Institute of Problems of Chemical Physics
[2] M. V. Lomonosov Moscow State University,undefined
来源
Russian Chemical Bulletin | 2019年 / 68卷
关键词
diarylhydroxylamines; halogenation; electrophilic substitution; reductive halogenation;
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摘要
Unlike most arenes, N, N-bis(4-tert-butylphenyl)hydroxylamine reacts with Br2via the reductive bromination mechanism. Here, two hydrogens in ortho positions of benzene rings are substituted by Br2 and provide two-electron reduction of hydroxylamine to amine.
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页码:1293 / 1297
页数:4
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