Mercury(II) diphosphate, Hg2P2O7

被引：25
|
作者：
Weil, P
Glaum, R
机构：
[1] Inst. F. Anorganische Analyt. Chem., Justus-Liebig-Univ. Gießen, D-35392 Gießen
来源：
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | 1997年 / 53卷
关键词：
D O I：
10.1107/S0108270197003879
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Mercury(II) diphosphate, Hg2P2O7, belongs to the M2X2O7 family of compounds with dichromate-type crystal structures and is isotypic with Cd2P2O7. The structure consists of alternating layers built from P2O7 groups and highly distorted HgO6 polyhedra with bond distances in the ranges 2.120(6) less than or equal to d(Hg1O(6)) less than or equal to 2.793 (7) Angstrom and 2.208 (6) less than or equal to d(Hg2O(6)) less than or equal to 2.509(6) Angstrom. The diphosphate anion has a P-O-P bridging angle of 133.4(4)degrees. The average P-O bond length is 1.604 Angstrom for bridging and 1.524 Angstrom for terminal bonds. [Hg1(2)O(10)] and [Hg2(2)O(10)] form chains running along [110] through edge-sharing dimers. These chains link to form layers parallel to ((1) over bar 10) via common vertices.
引用
收藏
页码：1000 / 1003
页数：4
相关论文
共 50 条
  • [21] Mercury nonstoichiometry of the Hg1-xBa2CuO4+δ superconductor and the P(Hg)-P(O2)-T phase diagram of the Hg-Ba-Cu-O system
    Alyoshin, VA
    Mikhailova, DA
    Rudnyi, EB
    Antipov, EV
    PHYSICA C-SUPERCONDUCTIVITY AND ITS APPLICATIONS, 2002, 383 (1-2): : 59 - 74
  • [22] STRUCTURAL ORDER IN COMPLEXES OF THE A(II)B(II)P(2)O(7) SERIES - BAPBP2O7, PBCOP2O7, PBMNP2O7 AND PBCUP2O7
    ELMARZOUKI, A
    BOUKHARI, A
    HOLT, EM
    BERRADA, A
    JOURNAL OF ALLOYS AND COMPOUNDS, 1995, 227 (02) : 125 - 130
  • [23] SUR LE DIPHOSPHATE MONOSIDIQUE NAH3P2O7
    NORBERT, A
    DAUTEL, C
    COMPTES RENDUS HEBDOMADAIRES DES SEANCES DE L ACADEMIE DES SCIENCES SERIE C, 1966, 262 (21): : 1534 - &
  • [24] Vibrational spectra and thermal dehydration of Co2P2O7•6H2O diphosphate
    Harcharras, M
    Ennaciri, A
    Capitelli, F
    Mattei, G
    VIBRATIONAL SPECTROSCOPY, 2003, 33 (1-2) : 189 - 196
  • [25] Thermal dehydration and infrared studies of Mg2P2O7•6H2O diphosphate
    Harcharras, M
    Ennaciri, A
    Khay, N
    Brouzi, K
    PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS, 2003, 178 (06) : 1247 - 1254
  • [26] A MOLYBDENUM(V) DIPHOSPHATE WITH A TUNNEL STRUCTURE - BETA-K2MO2O4P2O7
    GUESDON, A
    LECLAIRE, A
    BOREL, MM
    GRANDIN, A
    RAVEAU, B
    JOURNAL OF SOLID STATE CHEMISTRY, 1995, 114 (02) : 481 - 485
  • [27] STRUCTURE OF AN AMMONIUM MOLYBDENYL DIPHOSPHATE - (NH4)2MOO2P2O7
    AVERBUCHPOUCHOT, MT
    ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1988, 44 : 2046 - 2048
  • [28] Potassium trinickel(II) orthophosphate diphosphate, KNi3(PO4)P2O7
    Moutataouia, Meryem
    Lamire, Mohammed
    Saadi, Mohamed
    El Ammari, Lahcen
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2014, 70 : I5 - +
  • [29] Mercury(II) polyphosphate, Hg(PO3)2
    Weil, Matthias
    Glaum, Robert
    Acta Crystallographica Section C: Crystal Structure Communications, 2000, 56 (02) : 133 - 135
  • [30] Mercury(II) polyphosphate, Hg(PO3)2
    Weil, M
    Glaum, R
    ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY, 2000, 56 (pt 2): : 133 - 135
12345