Potassium trinickel(II) orthophosphate diphosphate, KNi3(PO4)P2O7

被引：3
|
作者：
Moutataouia, Meryem [1 ]
Lamire, Mohammed [1 ]
Saadi, Mohamed
El Ammari, Lahcen [2 ]
机构：
[1] Fac Sci Ain Chock, Lab Phys Chim Mat Inorgan, Casablanca, Morocco
[2] Univ Mohammed V Agdal, Fac Sci, Lab Chim Solide Appliquee, Rabat, Morocco
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2014年 / 70卷
关键词：
D O I：
10.1107/S1600536813034089
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
The structure of the title compound is characterized by the presence of two different anions, (PO4)(3-) and (P2O7)(4-) with an eclipsed conformation. The crystal structure consists of edge-sharing [NiO6] octahedra forming an [Ni3O14] chain running parallel to [001]. Adjacent chains are connected through edges and apices to PO4 and P2O7 groups in such a way as to build a three-dimensional host lattice. The resulting framework presents intersecting tunnels running along [010] and [101] in which the 11-coordinated potassium cation is located. The crystal structure of this new phosphate probably represents a new structural type.
引用
收藏
页码：I5 / +
页数：8
相关论文
共 50 条
  • [1] Heptasodium tetraaluminium tetrakis(diphosphate) orthophosphate, Na7Al4(P2O7)4(PO4)
    Zhao, Dan
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2011, 67 : I64 - +
  • [2] REDDISH-BROWN POTASSIUM-NICKEL(II) MONO-DIPHOSPHATE(V), K2NI4(PO4)2(P2O7)
    LADWIG, G
    WORZALA, H
    ZEITSCHRIFT FUR CHEMIE, 1978, 18 (10): : 374 - 375
  • [3] Na7Cr4(P2O7)(4)PO4
    Fakhar, Noura Bourguiba
    Zid, Mohamed Faouzi
    Driss, Ahmed
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2013, 69 : I27 - +
  • [4] STRUCTURE OF AN ACID PHOSPHATE OF POTASSIUM, K2H5(PO4,P2O7)
    LARBOT, A
    DURAND, J
    VILMINOT, S
    NORBERT, A
    ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE, 1981, 37 (MAY): : 1023 - 1027
  • [5] A comparative study of Li8NaV3(P2O7)3(PO4)2 and Li9V3(P2O7)3(PO4)2: Synthesis, structure and electrochemical properties
    Kuang, Quan
    Zhao, Yanming
    Dong, Youzhong
    Fan, Qinghua
    Lin, Xinghao
    Liu, Xudong
    JOURNAL OF POWER SOURCES, 2016, 306 : 337 - 346
  • [6] HYDROTHERMAL SYNTHESIS AND CRYSTAL-STRUCTURES OF BA2FE3H(PO4)2(P2O7)2 AND BA2V3H(PO4)2(P2O7)2
    DVONCOVA, E
    LII, KH
    LI, CH
    CHEN, TM
    JOURNAL OF SOLID STATE CHEMISTRY, 1993, 106 (02) : 485 - 492
  • [7] Thallium titanium phosphate, Tl3Ti3O(PO4)3(P2O7)
    Harrison, WTA
    ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1999, 55 : 1200 - 1203
  • [8] Phosphates with Two Types of Isolated P-O Groups: Noncentrosymmetric Na6Sr2Bi3(PO4)(P2O7)4 and Centrosymmetric Cs2CaBi2(PO4)2(P2O7)
    Yan, Yu
    Yu, Hongwei
    Zhou, Boru
    Hu, Zhanggui
    Wang, Jiyang
    Wu, Yicheng
    Wu, Hongping
    INORGANIC CHEMISTRY, 2023, 62 (21) : 8064 - 8068
  • [9] Synthesis and structure of a new phosphate Na4Ni3(PO4)(2)P2O7
    Nagornyi, PG
    Kapshuk, AA
    Sobolev, AN
    Golego, NV
    KRISTALLOGRAFIYA, 1996, 41 (05): : 835 - 838
  • [10] Crystal structure and ionic conductivity of AgCr2(PO4)(P2O7)
    Ayed, Brahim
    COMPTES RENDUS CHIMIE, 2012, 15 (07) : 603 - 608
12345