Homologous series of layered tetradymite-like compounds in Bi-Te and GeTe-Bi2Te3 systems

被引：28
|
作者：
Shelimova, LE [1 ]
Karpinskii, OG
Kosyakov, VI
Shestakov, VA
Zemskov, VS
Kuznetsov, FA
机构：
[1] Russian Acad Sci, AA Baikov Met Inst, Moscow 117901, Russia
[2] Russian Acad Sci, Siberian Branch, Inst Inorgan Chem, Novosibirsk, Russia
来源：
JOURNAL OF STRUCTURAL CHEMISTRY | 2000年 / 41卷 / 01期
关键词：
D O I：
10.1007/BF02684732
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Formation of the homologous series of layered compounds nBi(2) . mBi(2)Te(3) and nGeTe . mBi(2)Te(3) is analyzed. For both series, the crystal structure contains two-layer (Bi-2 or GeTe) and five-layer (Bi2Te3) packets perpendicular to the c axis. Unlike the Bi-2 packers, the GeTe packets do not retain their individually during crystal structure formation; they are linked to the Bi2Te3 five-layer packets to form new multilayer packets leading to a considerable change in the character of interatomic interactions.
引用
收藏
页码：81 / 87
页数：7
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