Homologous series of layered tetradymite-like compounds in Bi-Te and GeTe-Bi2Te3 systems

被引：28

作者：

Shelimova, LE ^{[1
]}

Karpinskii, OG

Kosyakov, VI

Shestakov, VA

Zemskov, VS

Kuznetsov, FA

机构：

[1] Russian Acad Sci, AA Baikov Met Inst, Moscow 117901, Russia

[2] Russian Acad Sci, Siberian Branch, Inst Inorgan Chem, Novosibirsk, Russia

来源：

JOURNAL OF STRUCTURAL CHEMISTRY | 2000年 / 41卷 / 01期

关键词：

D O I：

10.1007/BF02684732

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Formation of the homologous series of layered compounds nBi(2) . mBi(2)Te(3) and nGeTe . mBi(2)Te(3) is analyzed. For both series, the crystal structure contains two-layer (Bi-2 or GeTe) and five-layer (Bi2Te3) packets perpendicular to the c axis. Unlike the Bi-2 packers, the GeTe packets do not retain their individually during crystal structure formation; they are linked to the Bi2Te3 five-layer packets to form new multilayer packets leading to a considerable change in the character of interatomic interactions.

引用

页码：81 / 87

页数：7

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