Spirocyclic phosphazene complexes of arsenic(III): Synthesis and characterization

被引：7

作者：

Paul, Y ^{[1
]}

Pandey, SK ^{[1
]}

机构：

[1] Univ Jammu, Dept Chem, Jammu 180006, Jammu & Kashmir, India

来源：

PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS | 2003年 / 178卷 / 01期

关键词：

dioxarsenane; dioxarsolane; heterometallacyclophosphazene; metallaphosphazene; phosphazene-glycolate;

D O I：

10.1080/10426500307773

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A new acyclic phosphazene ligand, [HN(PPh2NPh)(2)] (A) has been synthesized and characterized. Spirocyclic phosphazene-glycolate complexes of arsenic(III) with ligand (A) and [HN(PPh2NSiMe3)(2)] (B), having the general formula [N(PPh2NPh)(2)AsOGO] and [N(PPh2NSiMe3)(2)AsOGO] (where G = -CH2CH2-, -CHMeCH2-, -CHMeCH2CMe2-, -CH2CH2CH2-, or -CMe2CMe2-) also have been synthesized by their reaction with chloro dioxarsolanes and -arsenanes in anhydrous medium. These moisture sensitive complexes are characterized by elemental analysis, IR, NMR (H-1, C-13, and P-31), and mass spectral data which have been discussed in relation to plausible structure for these arsenic(III) derivatives.

引用

页码：159 / 170

页数：12

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