Spirocyclic phosphazene complexes of arsenic(III): Synthesis and characterization

被引：7

作者：

Paul, Y ^{[1
]}

Pandey, SK ^{[1
]}

机构：

[1] Univ Jammu, Dept Chem, Jammu 180006, Jammu & Kashmir, India

来源：

PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS | 2003年 / 178卷 / 01期

关键词：

dioxarsenane; dioxarsolane; heterometallacyclophosphazene; metallaphosphazene; phosphazene-glycolate;

D O I：

10.1080/10426500307773

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A new acyclic phosphazene ligand, [HN(PPh2NPh)(2)] (A) has been synthesized and characterized. Spirocyclic phosphazene-glycolate complexes of arsenic(III) with ligand (A) and [HN(PPh2NSiMe3)(2)] (B), having the general formula [N(PPh2NPh)(2)AsOGO] and [N(PPh2NSiMe3)(2)AsOGO] (where G = -CH2CH2-, -CHMeCH2-, -CHMeCH2CMe2-, -CH2CH2CH2-, or -CMe2CMe2-) also have been synthesized by their reaction with chloro dioxarsolanes and -arsenanes in anhydrous medium. These moisture sensitive complexes are characterized by elemental analysis, IR, NMR (H-1, C-13, and P-31), and mass spectral data which have been discussed in relation to plausible structure for these arsenic(III) derivatives.

引用

页码：159 / 170

页数：12

共 50 条

[21] Synthesis and characterization of porphyrin complexes of iron(III) and manganese(III)
Krishna, V
Agarwal, DD
Bayrappa, G
Rastogi, R
INDIAN JOURNAL OF CHEMISTRY SECTION A-INORGANIC BIO-INORGANIC PHYSICAL THEORETICAL & ANALYTICAL CHEMISTRY, 1998, 37 (10): : 918 - 920
[22] Synthesis and spectroscopic characterization of complexes of Y(III) and Nd(III)
Kong, FR
Yang, YL
Zhu, HJ
SPECTROSCOPY AND SPECTRAL ANALYSIS, 1999, 19 (03) : 336 - 338
[23] Synthesis and Characterization of Bismuth(III) and Antimony(III) Calixarene Complexes
Liu, Lihua
Zakharov, Lev N.
Golen, James A.
Rheingold, Arnold L.
Hanna, Tracy A.
INORGANIC CHEMISTRY, 2008, 47 (23) : 11143 - 11153
[24] Synthesis and characterization of dialkyldithiophosphate complexes of gallium(III)
Pahari, D
Jain, VK
MAIN GROUP METAL CHEMISTRY, 1997, 20 (11): : 691 - 696
[25] SYNTHESIS AND CHARACTERIZATION OF COMPLEXES OF NEODYMIUM(III) WITH PIPERAZINES
TRIKHA, AK
INORGANICA CHIMICA ACTA, 1987, 139 (1-2) : 155 - 157
[26] SYNTHESIS AND CHARACTERIZATION OF SOME COBALT(III) COMPLEXES
COULTER, G
KRISHNAMURTHY, M
JOURNAL OF INORGANIC & NUCLEAR CHEMISTRY, 1977, 39 (11): : 1969 - 1970
[27] SYNTHESIS AND CHARACTERIZATION OF DIORGANOANTIMONY(III) COMPLEXES OF THIOSEMICARBAZONES
GUPTA, R
SINGH, YP
RAI, AK
PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS, 1990, 53 (1-4): : 397 - 401
[28] REDUCTION OF CHLOROTHALLIUM(III) COMPLEXES BY ARSENIC(III)
SHARMA, PD
GUPTA, YK
AUSTRALIAN JOURNAL OF CHEMISTRY, 1973, 26 (10) : 2115 - 2122
[29] Synthesis and characterization of chromium(III) complexes.
Wong, CN
Simonis, U
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2002, 224 : U71 - U71
[30] Synthesis and Characterization of Benziloximato Complexes of Antimony(III)
Synth React Inorg Metal Org Chem, 10 (1509):

← 1 2 3 4 5 →