NMR study on dynamics of protons in Rb3H(SeO4)2

被引:0
|
作者
Matsuo, Y [1 ]
Takahashi, K [1 ]
Hisada, K [1 ]
Ikehata, S [1 ]
机构
[1] Sci Univ Tokyo, Fac Sci, Dept Appl Phys, Shinjuku Ku, Tokyo 1628601, Japan
关键词
Rb3H(SeO4)(2); NMR; ferroelastic phase transition;
D O I
暂无
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Proton NMR spectra were measured in the region from 300K to 500K, in order to clear the proton dynamics in the a(h)-b(h) plane of hexagonal system in paraelastic phase for Rb3H(SeO4)(2), directly. It was found from the NMR spectra that the hydrogen bonds between SeO(4)ions should be broken with the rearrangement process in the a(h)-b(h) plane above T-c. Moreover, from the analysis of the second and forth moments, we determined the area of proton motion in the a(h)-b(h) plane.
引用
收藏
页码:1237 / 1244
页数:8
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